Wang Ying, Guo Shaohua, Pei Zhongshi, Zhan Shizuo, Lin Senlin, Ma Kezheng, Lei Junwen, Yi Junyan
School of Transportation Science and Engineering, Harbin Institute of Technology, No. 73 Huanghe Road, Nangang District, Harbin 150090, China.
Liaoning Provincial Transportation Planning and Design Institute Co., Ltd., No. 42, Lidao Road, Heping District, Shenyang 110166, China.
Materials (Basel). 2024 Mar 22;17(7):1454. doi: 10.3390/ma17071454.
SBS (styrene-butadiene-styrene block copolymer) is a thermoplastic elastomer with properties most similar to rubber. SBS asphalt modifier is mainly composed of a styrene-butadiene-styrene block copolymer with a certain amount of additives and stabilizers. SBS-modified asphalt binder has always been the most commonly used pavement material both domestically and internationally. However, conventional wet-process SBS-modified asphalt binder requires manufacturers to produce it in advance and transport it to a mixing plant for blending. This has provided an opportunity for unscrupulous businesses to reduce the amount of SBS by adding other substances, allowing inferior asphalt binder to pass inspections undetected. At the same time, conventional wet-process SBS-modified asphalt tends to undergo phase separation and experience a decline in performance as the storage time increases. However, dry-process SBS-modified asphalt can be directly added at the mixing plant, effectively addressing the issues associated with conventional wet-process SBS-modified asphalt. It also helps to reduce environmental pollution to a certain extent. This study investigates the extraction process of dry-process SBS-modified asphalt binder. It clarifies the performance and modification mechanisms of two types of dry-process SBS-modified asphalt binder at different dosages through various testing methods, including basic indicators, rheological properties, infrared spectroscopy, and fluorescence microscopy. The results indicate that due to the incorporation of oil, crosslinker, solubilizer, and other substances into dry-process SBS modifier, there is a small amount of chemical reaction with asphalt in the melting process. The high- and low-temperature properties and fatigue properties of the two dry-process SBS-modified asphalt binders at a 7% dosage are close to wet SBS-modified asphalt binder at a 5% dosage.
苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)是一种热塑性弹性体,其性能与橡胶最为相似。SBS沥青改性剂主要由苯乙烯-丁二烯-苯乙烯嵌段共聚物以及一定量的添加剂和稳定剂组成。SBS改性沥青结合料一直是国内外最常用的路面材料。然而,传统的湿法SBS改性沥青结合料需要制造商提前生产并运输到搅拌厂进行混合。这为不法商家通过添加其他物质来减少SBS用量提供了可乘之机,使得劣质沥青结合料得以蒙混过关。同时,传统的湿法SBS改性沥青随着储存时间的增加容易发生相分离,性能也会下降。而干法SBS改性沥青可以在搅拌厂直接添加,有效解决了传统湿法SBS改性沥青存在的问题,并且在一定程度上有助于减少环境污染。本研究对干法SBS改性沥青结合料的提取工艺进行了研究。通过包括基本指标、流变性能、红外光谱和荧光显微镜等各种测试方法,阐明了两种不同剂量的干法SBS改性沥青结合料的性能和改性机理。结果表明,由于在干法SBS改性剂中加入了油、交联剂、增溶剂等物质,在熔融过程中与沥青发生了少量化学反应。两种7%剂量的干法SBS改性沥青结合料的高低温性能和疲劳性能接近5%剂量的湿法SBS改性沥青结合料。