Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, National Observations and Research Station for Wetland Ecosystems of the Yangtze Estuary, IRDR International Center of Excellence on Risk Interconnectivity and Governance on Weather, Department of Environmental Science & Engineering, Fudan University, Shanghai 200433, Peoples' Republic of China.
State Key Laboratory of Surface Physics and Department of Physics, Human Phenome Institute, Academy for Engineering and Technology, Key Laboratory of Micro and Nano Photonic Structures (Ministry of Education), Yiwu Research Institute of Fudan University, Fudan University, Shanghai 200433, Peoples' Republic of China.
Environ Sci Technol. 2024 May 28;58(21):9091-9101. doi: 10.1021/acs.est.3c11021. Epub 2024 May 6.
People of all ages consume salt every day, but is it really just salt? Plastic nanoparticles [nanoplastics (NPs)] pose an increasing environmental threat and have begun to contaminate everyday salt in consumer goods. Herein, we developed a combined surface enhanced Raman scattering (SERS) and stimulated Raman scattering (SRS) approach that can realize the filtration, enrichment, and detection of NPs in commercial salt. The Au-loaded (50 nm) anodic alumina oxide substrate was used as the SERS substrate to explore the potential types of NP contaminants in salts. SRS was used to conduct imaging and quantify the presence of the NPs. SRS detection was successfully established through standard plastics, and NPs were identified through the match of the hydrocarbon group of the nanoparticles. Simultaneously, the NPs were quantified based on the high spatial resolution and rapid imaging of the SRS imaging platform. NPs in sea salts produced in Asia, Australasia, Europe, and the Atlantic were studied. We estimate that, depending on the location, an average person could be ingesting as many as 6 million NPs per year through the consumption of sea salt alone. The potential health hazards associated with NP ingestion should not be underestimated.
不同年龄段的人每天都要摄入盐,但它真的只是盐吗?塑料纳米颗粒(NPs)对环境构成的威胁日益严重,已开始污染消费品中的日常用盐。在此,我们开发了一种结合表面增强拉曼散射(SERS)和受激拉曼散射(SRS)的方法,可实现对商业盐中 NPs 的过滤、富集和检测。负载金的(50nm)阳极氧化铝基底被用作 SERS 基底,以探索盐中潜在的 NP 污染物类型。SRS 用于进行成像并定量存在的 NPs。通过标准塑料成功建立了 SRS 检测,并通过纳米颗粒的碳氢基团的匹配来识别 NPs。同时,根据 SRS 成像平台的高空间分辨率和快速成像对 NPs 进行定量。对亚洲、澳大拉西亚、欧洲和大西洋生产的海盐中的 NPs 进行了研究。我们估计,根据位置的不同,仅通过食用海盐,一个人每年可能会摄入多达 600 万个 NPs。与 NP 摄入相关的潜在健康危害不应被低估。