Self-assembly of a supramolecular spin-crossover tetrahedron.

作者信息

Nielsen Hannah H, Vilariño Pol, Rodríguez Gemma, Trepard Florian, Roubeau Olivier, Aromí Guillem, Aguilà David

机构信息

Departament de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain.

Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark.

出版信息

Dalton Trans. 2024 Jun 10;53(23):9792-9797. doi: 10.1039/d4dt00578c.

DOI:10.1039/d4dt00578c

PMID:38787740

Abstract

A new mononuclear iron(II) SCO compound featuring H-bonding donor and acceptor units has been synthesized and exploited to produce a purely supramolecular switchable [Fe] tetrahedron. Magnetic and crystallographic measurements evidence a singular magnetic behavior for each of the four Fe(II) centers of the generated architecture and underscore the potential of this strategy to develop novel SCO materials.

摘要