Liu Huating, Huang Zongyu, Qiao Hui, Qi Xiang
School of Electrical and Electronic Engineering, Wuhan Polytechnic University, Wuhan 430023, China.
Hunan Key Laboratory for Micro-Nano Energy Materials and Devices, School of Physics and Optoelectronic, Xiangtan University, Xiangtan, 411105, China.
Phys Chem Chem Phys. 2024 Jun 26;26(25):17423-17442. doi: 10.1039/d4cp01261e.
In recent years, doping engineering, which is widely studied in theoretical and experimental research, is an effective means to regulate the crystal structure and physical properties of two-dimensional materials and expand their application potential. Based on different types of element dopings, different 2D materials show different properties and applications. In this paper, the characteristics and performance of rich layered 2D materials under different types of doped elements are comprehensively reviewed. Firstly, 2D materials are classified according to their crystal structures. Secondly, conventional experimental methods of charge doping and heterogeneous atom substitution doping are summarized. Finally, on the basis of various theoretical research results, the properties of several typical 2D material representatives under charge doping and different kinds of atom substitution doping as well as the inspiration and expansion of doping systems for the development of related fields are discussed. Through this review, researchers can fully understand and grasp the regulation rules of different doping engineering on the properties of layered 2D materials with different crystal structures. It provides theoretical guidance for further improving and optimizing the physical properties of 2D materials, improving and enriching the relevant experimental research and device application development.
近年来,掺杂工程在理论和实验研究中得到广泛关注,是调控二维材料晶体结构和物理性质、拓展其应用潜力的有效手段。基于不同类型的元素掺杂,不同的二维材料展现出不同的性质和应用。本文全面综述了富层状二维材料在不同类型掺杂元素下的特性与性能。首先,根据晶体结构对二维材料进行分类。其次,总结了电荷掺杂和异质原子取代掺杂的常规实验方法。最后,基于各种理论研究成果,讨论了几种典型二维材料代表在电荷掺杂和不同种类原子取代掺杂下的性质,以及掺杂体系对相关领域发展的启发与拓展。通过这篇综述,研究人员能够充分理解和掌握不同掺杂工程对具有不同晶体结构的层状二维材料性质的调控规律。它为进一步改善和优化二维材料的物理性质、改进和丰富相关实验研究以及器件应用开发提供了理论指导。