Jameson Caolan, Devine Declan M, Keane Gavin, Gately Noel M
PRISM Research Institute, Technological University of the Shannon: Midlands Midwest, Athlone Campus, University Road, N37 HD68 Athlone, Ireland.
Centre for Industrial Service & Design, Technological University of the Shannon: Midlands Midwest, Athlone Campus, University Road, N37 HD68 Athlone, Ireland.
Materials (Basel). 2024 May 29;17(11):2625. doi: 10.3390/ma17112625.
This study investigates the effect of extrusion screw speed and carbon nanotube (CNT) concentration on the thermal, mechanical, and electromagnetic interference shielding effectiveness (EMI SE) properties of Polycarbonate (PC)/acrylonitrile-butadiene-styrene (ABS) and its polymer nanocomposites (PNCs) by means of design of experiments (DoE) approach. A masterbatch method was employed to obtain the best dispersion of the CNTs throughout the polymer matrix. This study evaluates the thermo-mechanical characterisation of the polymers and PNCs at varying screw speeds to assess filler matrix bonding. The results highlight that CNT concentration has a significant effect on all mechanical properties, while screw speed only affects the Charpy impact strength and flexural properties of the samples. Compounding at 200 rpm has the best flexural and tensile strength, which is attributed to the best filler matrix bonding (highest storage modulus) of the PNCs. The best EMI SE results were obtained at 10 wt.% CNTs. This research contributes valuable insights into the effect of CNT concentration and extrusion screw speed on the mechanical, thermal and EMI SE properties of PC/ABS and its PNCs.
本研究通过实验设计(DoE)方法,研究了挤出螺杆速度和碳纳米管(CNT)浓度对聚碳酸酯(PC)/丙烯腈-丁二烯-苯乙烯(ABS)及其聚合物纳米复合材料(PNC)的热性能、机械性能和电磁干扰屏蔽效能(EMI SE)的影响。采用母料法使碳纳米管在整个聚合物基体中获得最佳分散。本研究评估了在不同螺杆速度下聚合物和聚合物纳米复合材料的热机械特性,以评估填料与基体的结合情况。结果表明,碳纳米管浓度对所有机械性能都有显著影响,而螺杆速度仅影响样品的夏比冲击强度和弯曲性能。在200转/分钟的转速下进行混合具有最佳的弯曲强度和拉伸强度,这归因于聚合物纳米复合材料的最佳填料与基体结合(最高储能模量)。在碳纳米管含量为10 wt.%时获得了最佳的电磁干扰屏蔽效能结果。本研究为碳纳米管浓度和挤出螺杆速度对PC/ABS及其聚合物纳米复合材料的机械性能、热性能和电磁干扰屏蔽效能的影响提供了有价值的见解。