Wang Tianlei, Chen Yao, Jing Xiudang, Wang Xueping, Zhang Lei, Yang Peisen
School of Materials Science and Engineering, Tianjin Chengjian University, Tianjin 300384, China.
Tianjin Zhaoyang Environmental Technology Group Co., Ltd., Tianjin 300384, China.
Materials (Basel). 2024 Jun 27;17(13):3167. doi: 10.3390/ma17133167.
Lightweight geopolymers have the advantages of a wide source of raw materials, chemical corrosion resistance, high mechanical strength and excellent durability, and are expected to replace traditional building insulation materials. In this paper, a green bio-based foaming agent with a small 1 h settlement distance, high average foaming multiple and low bleeding ratio was obtained by a Cetyltrimethylammonium Bromide/yeast solution. When the amount of Cetyltrimethylammonium Bromide is 0.50 wt%, the foam prepared by the yeast and Cetyltrimethylammonium Bromide solution exhibits the improved 1 h settlement distance, the large average foaming multiple, the small bleeding ratio and uniform foam size. Subsequently, a lightweight geopolymer based on metakaolin and fly ash (or silica fume) was successfully prepared by the bio-based foaming agent, and the effects of different foam content on the properties of the geopolymer, such as dry density, water absorption, thermal conductivity, compressive strength and morphology, were studied. With an increase in foam content, the dry density, thermal conductivity and compressive strength of the geopolymer gradually decrease, the water absorption increases, regardless of whether silica fume or fly ash are added. Herein, it is confirmed that the foaming agent based on yeast can be effectively used to prepare lightweight geopolymers, which can provide vast opportunities to turn into candidates for novel inorganic thermal insulation materials.
轻质地质聚合物具有原材料来源广泛、耐化学腐蚀、机械强度高和耐久性优异等优点,有望取代传统建筑保温材料。本文通过十六烷基三甲基溴化铵/酵母溶液获得了一种沉降距离小、平均发泡倍数高、泌水率低的绿色生物基发泡剂。当十六烷基三甲基溴化铵的用量为0.50 wt%时,由酵母和十六烷基三甲基溴化铵溶液制备的泡沫表现出沉降距离减小、平均发泡倍数增大、泌水率降低且泡沫尺寸均匀的特点。随后,利用该生物基发泡剂成功制备了基于偏高岭土和粉煤灰(或硅灰)的轻质地质聚合物,并研究了不同泡沫含量对地质聚合物性能(如干密度、吸水率、导热系数、抗压强度和形态)的影响。随着泡沫含量的增加,无论是否添加硅灰或粉煤灰,地质聚合物的干密度、导热系数和抗压强度均逐渐降低,吸水率增加。在此证实,基于酵母的发泡剂可有效用于制备轻质地质聚合物,这为其成为新型无机保温材料的候选材料提供了广阔机遇。