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聚乙烯醇-琥珀聚糖可生物降解薄膜的结构与物理化学性质

Structural and Physiochemical Properties of Polyvinyl Alcohol-Succinoglycan Biodegradable Films.

作者信息

Jeong Jae-Pil, Yoon Inwoo, Kim Kyungho, Jung Seunho

机构信息

Department of Bioscience and Biotechnology, Konkuk University, Seoul 05029, Republic of Korea.

Department of System Biotechnology, Konkuk University, Seoul 05029, Republic of Korea.

出版信息

Polymers (Basel). 2024 Jun 24;16(13):1783. doi: 10.3390/polym16131783.

Abstract

Polyvinyl alcohol (PVA)-bacterial succinoglycan (SG) biodegradable films were developed through a solvent-casting method. Effects of the PVA/SG ratio on the thickness, transmittance, water holding capacity, and structural and mechanical properties were investigated by various analytical methods. All the prepared films were transparent and uniform, and XRD and FTIR analyses confirmed that PVA was successfully incorporated into SG. The films also showed excellent UV-blocking ability: up to close to 80% with increasing SG concentration. The formation of effective intermolecular interactions between these polymers was evidenced by their high tensile strength and moisture transport capacity. By measuring the biodegradation rate, it was confirmed that films with high SG content showed the fastest biodegradation rate over 5 days. These results confirm that PVA/SG films are eco-friendly, with both excellent biodegradability and effective UV-blocking ability, suggesting the possibility of industrial applications as a packaging material in various fields in the future.

摘要

通过溶液浇铸法制备了聚乙烯醇(PVA)-细菌琥珀聚糖(SG)可生物降解薄膜。采用多种分析方法研究了PVA/SG比例对薄膜厚度、透光率、持水能力以及结构和力学性能的影响。所有制备的薄膜均透明且均匀,XRD和FTIR分析证实PVA已成功掺入SG中。薄膜还表现出优异的紫外线阻挡能力:随着SG浓度的增加,紫外线阻挡率高达近80%。这些聚合物之间形成了有效的分子间相互作用,这通过它们的高拉伸强度和水分传输能力得到了证明。通过测量生物降解率,证实高SG含量的薄膜在5天内显示出最快的生物降解率。这些结果证实PVA/SG薄膜是环保的,具有优异的生物降解性和有效的紫外线阻挡能力,这表明未来有可能作为包装材料在各个领域进行工业应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b5b/11244272/18fdd4974569/polymers-16-01783-g001.jpg

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