聚[[μ-2-(苯并三唑-1-基)乙酸根-κO,O']氯(乙醇-κO)钴(II)]
Poly[[μ-2-(benzotriazol-1-yl)acetato-κ :': ]chlorido-(ethanol-κ)cobalt(II)].
作者信息
Zheng Yun-Yun, Su De-Sen, Yao Qing-Hua, Huang Min-Min
机构信息
Fujian Key Laboratory of Agro-Products Quality and Safety Institute of Quality Standards Testing Technology for Agro-products, Fujian Academy of Agricultural Sciences 247 Wu-Si Rd Fuzhou People's Republic of China.
出版信息
IUCrdata. 2024 Jul 5;9(Pt 7):x240630. doi: 10.1107/S2414314624006308. eCollection 2024 Jul.
In the title compound, [Co(CHNO)Cl(CHOH)] , the Co atoms adopt octa-hedral -CoNO and tetra-hedral CoClO coordination geometries (site symmetries and , respectively). The bridging μ-:: 2-(benzotriazol-1-yl)acetato ligands connect the octa-hedral cobalt nodes into (010) sheets and the CoCl fragments link the sheets into a tri-periodic network. The structure displays O-H⋯O hydrogen bonding and the ethanol mol-ecule is disordered over two orientations.
在标题化合物[Co(CHNO)Cl(CHOH)]中，钴原子采用八面体-CoNO和四面体CoClO配位几何构型（分别为点群对称性和）。桥连的μ-:: 2-(苯并三唑-1-基)乙酸根配体将八面体钴节点连接成(010)层，而CoCl片段将这些层连接成一个三维周期性网络。该结构存在O-H⋯O氢键，并且乙醇分子在两个取向之间无序分布。
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