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来自血莓的荧光碳点用于检测水中的铬离子及其在白光发光二极管中的应用。

Fluorescence Carbon Dots from Blood-Berries for Sensing Cr Ions in Water and Application in White Light Emitting Diode.

作者信息

Kamalarasan V, Venkateswaran C

机构信息

Department of Nuclear Physics, University of Madras, Guindy campus, Chennai, 600025, Tamil Nadu, India.

出版信息

J Fluoresc. 2024 Sep 10. doi: 10.1007/s10895-024-03916-1.

Abstract

Conventional techniques for identifying heavy metal ions in water are laborious and time-consuming. Therefore, it is necessary to create innovative sensing technologies that can detect with greater sensitivity and speed. Although there have been reports of optical-based assays utilising fluorescent nanomaterials, these assays usually rely on variations in signal strength. However, this approach has significant drawbacks when it comes to environmental monitoring. Fluorescence carbon dots (CDs) have been prepared by facile synthesis from Blood berries. A homemade heavy metal optical detector is constructed to accurately identify heavy metal ions, exclusively Cr ions in a water medium. Their optical emission signature varies based on the specific chromium ions in solution, and the emission intensity also changes depending on its concentration. The quenching behaviour is attributed to the interaction between the metallic cations and the fluorescent surface states of the carbon dots. Another application is the encapsulation of CDs in PVDF polymer to form a flexible film and use it as a phosphor for LED conversion.

摘要

用于识别水中重金属离子的传统技术既费力又耗时。因此,有必要开发出能够以更高灵敏度和速度进行检测的创新传感技术。尽管已有利用荧光纳米材料进行基于光学的检测的报道,但这些检测通常依赖于信号强度的变化。然而,在环境监测方面,这种方法存在显著缺陷。荧光碳点(CDs)已通过从血莓中简便合成而制备出来。构建了一种自制的重金属光学探测器,以准确识别水介质中的重金属离子,特别是铬离子。它们的光发射特征会根据溶液中特定的铬离子而变化,并且发射强度也会因其浓度而改变。猝灭行为归因于金属阳离子与碳点荧光表面态之间的相互作用。另一个应用是将碳点封装在聚偏氟乙烯(PVDF)聚合物中形成柔性薄膜,并将其用作LED转换的磷光体。

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