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油和热老化对丁腈橡胶密封件密封特性的影响

The Influence of Oil and Thermal Aging on the Sealing Characteristics of NBR Seals.

作者信息

Li Yiding, Wu Jian, Chen Zhihao, Zhang Ziqi, Su Benlong, Wang Youshan

机构信息

Center for Rubber Composite Materials and Structures, Harbin Institute of Technology, Weihai 264209, China.

National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, Harbin 150090, China.

出版信息

Polymers (Basel). 2024 Sep 2;16(17):2501. doi: 10.3390/polym16172501.

Abstract

Nitrile Butadiene Rubber (NBR) is widely used as a sealing material due to its excellent mechanical properties and good oil resistance. However, when using NBR material, the seal structure is unable to avoid the negative effects of rubber aging. Hence, the influence of oil and thermal aging on the characteristics of NBR seals was studied by coupling the mechanical behavioral changes with the tribological behavioral changes of NBR in oil and the thermal environment. For this paper, aging testing and compression testing of NBR were carried out. Additionally, friction testing between friction pairs under different aging times was carried out. The surface morphology of the NBR working surface under different aging conditions was also observed. Finally, coefficients of different test conditions were introduced into the finite element model of NBR seals. It can be seen from the results that the elastic modulus increased with the increase in aging time in the thermal oxidative aging testing. The elastic modulus after 7 days of thermal oxidative aging increased by 135.45% compared to the unaged case, and the elastic modulus after 7 days of oil aging increased by 15.03% compared to the unaged case. The compression set rate of NBR increased significantly with the increase in aging time and temperature. The coefficient of friction (COF) between friction pairs increased first and then decreased with the increase in aging time. The maximum contact pressure decreased by 2.43% between the shaft and sealing ring and decreased by 4.01% between the O-ring and groove. The proportion of the effective sealing area decreased by 3.05% between the shaft and sealing ring and decreased by 6.11% between the O-ring and groove. Furthermore, the sealing characteristics between the O-ring and groove were better than those between the shaft and sealing ring.

摘要

丁腈橡胶(NBR)因其优异的机械性能和良好的耐油性而被广泛用作密封材料。然而,在使用NBR材料时,密封结构无法避免橡胶老化的负面影响。因此,通过将NBR在油和热环境中的力学行为变化与摩擦学行为变化相结合,研究了油老化和热老化对NBR密封件特性的影响。针对本文,对NBR进行了老化试验和压缩试验。此外,还进行了不同老化时间下摩擦副之间的摩擦试验。还观察了不同老化条件下NBR工作表面的形貌。最后,将不同试验条件下的系数引入NBR密封件的有限元模型。结果表明,在热氧化老化试验中,弹性模量随老化时间的增加而增大。热氧化老化7天后的弹性模量比未老化时增加了135.45%,油老化7天后的弹性模量比未老化时增加了15.03%。NBR的压缩永久变形率随老化时间和温度的增加而显著增大。摩擦副之间的摩擦系数(COF)随老化时间的增加先增大后减小。轴与密封环之间的最大接触压力降低了2.43%,O形环与凹槽之间的最大接触压力降低了4.01%。轴与密封环之间的有效密封面积比例降低了3.05%,O形环与凹槽之间的有效密封面积比例降低了6.11%。此外,O形环与凹槽之间的密封特性优于轴与密封环之间的密封特性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/55f9/11397856/af59635a7652/polymers-16-02501-g001.jpg

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