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偏弧对Q235/304异种钢焊接接头组织与耐蚀性的影响

Effect of Bias Arc on Microstructure and Corrosion Resistance of Q235/304 Dissimilar-Steel-Welded Joints.

作者信息

Li Lin, Ma Rongcai, Yang Cheng, Liu Tie, Sun Guorui, Li Wenlong, Jia Chuanchuan, Chen Chao, Hu Fengya

机构信息

State Key Laboratory of Metal Material for Marine Equipment and Application, Anshan 114003, China.

Research Institute of Ansteel Group, Anshan 114003, China.

出版信息

Materials (Basel). 2024 Aug 27;17(17):4234. doi: 10.3390/ma17174234.

Abstract

To fully exploit the advantages of steel, the welding connection of dissimilar steels has been developed. In this work, the metallographic microstructures, elemental distributions, and electrochemical corrosion properties of the Q235 and 304 welds under different bias arcs were investigated. The arc bias caused the Q235-side heat-affected zone to widen, the microstructure consisted of ferrite and pearlite, and the ratio varied with decreasing distance from the fusion line. Elemental scans show that Cr and Ni concentration gradients exist near the fusion line. The 304-stainless-steel-side heat-affected zone was mainly composed of austenite grains, and the fusion zone was narrower but prone to cracking. Electrochemical tests revealed that 304 stainless steel had the best corrosion resistance, while Q235 had the worst corrosion resistance, and that the welded joints with an arc bias toward the 304 side had the best corrosion resistance. The samples' the passivation film which formed via electrochemical polarization had limited stability, but the over-passivation potential could be used as a reference for corrosion resistance. Overall, the arc bias and weld material properties significantly affected the microstructure and corrosion resistance of the joints.

摘要

为了充分发挥钢材的优势,异种钢的焊接连接技术得到了发展。在这项工作中,研究了不同偏弧条件下Q235和304焊缝的金相组织、元素分布和电化学腐蚀性能。电弧偏置导致Q235侧热影响区变宽,其微观结构由铁素体和珠光体组成,且该比例随距熔合线距离的减小而变化。元素扫描表明,熔合线附近存在Cr和Ni浓度梯度。304不锈钢侧热影响区主要由奥氏体晶粒组成,熔合区较窄但易开裂。电化学测试表明,304不锈钢的耐蚀性最佳,Q235的耐蚀性最差,且电弧偏向304侧的焊接接头耐蚀性最佳。通过电化学极化形成的样品钝化膜稳定性有限,但过钝化电位可作为耐蚀性的参考。总体而言,电弧偏置和焊接材料性能显著影响接头的微观结构和耐蚀性。

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