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原位合成TiC/6061纳米复合材料的微观结构、力学性能及强化机制

Microstructure, mechanical properties and strengthening mechanism of in-situ synthesized TiC/6061 nanocomposites.

作者信息

Zhuang Weibin, Li Jinghui, Cao Qing, Qin Longjian, Jia Jing, Liu Jingfu

机构信息

School of Materials Science and Engineering, Liaoning Technical University, Fuxin, 123000, China.

出版信息

Heliyon. 2024 Aug 29;10(17):e37122. doi: 10.1016/j.heliyon.2024.e37122. eCollection 2024 Sep 15.

Abstract

In-situ synthesized 1 wt%, 3 wt% and 5 wt%TiC/6061 nanocomposites were prepared by the reaction using Al-KTiF-C as starting materials. Microstructure, mechanical properties and strengthening mechanism of the nanocomposites were investigated. SEM observation illustrates the in-situ synthesized ceramic TiC particles show shape of a polygon and its average size is 60 nm. TEM results show that the interface between the Al matrix and TiC reinforcement is clear and no reaction products can be found. Grain refining can be observed in the composites, as the TiC content increased from 0 wt% to 3 wt%. However, grain coarsening appears in the 5 wt%TiC/6061 composites. As increasing the TiC content from 0 wt% to 5 wt%, the mechanical properties of the composites increase firstly and then decreases. The Vickers hardness, yield strength, tensile strength and elongation of the as-cast 3 wt%TiC/6061 composites achieve the maximum value of 80.7 HV, 135 MPa, 202 MPa and 15.3 %, respectively. Strengthening mechanisms of the TiC/6061 nanocomposites is the micromechanical strengthening mechanisms. As the TiC content increasing, CTE strengthening plays an important role.

摘要

以Al-KTiF-C为原料,通过反应制备了原位合成的1 wt%、3 wt%和5 wt%的TiC/6061纳米复合材料。研究了纳米复合材料的微观结构、力学性能和强化机制。扫描电子显微镜(SEM)观察表明,原位合成的陶瓷TiC颗粒呈多边形,平均尺寸为60 nm。透射电子显微镜(TEM)结果表明,Al基体与TiC增强体之间的界面清晰,未发现反应产物。随着TiC含量从0 wt%增加到3 wt%,复合材料中可观察到晶粒细化。然而,在5 wt%TiC/6061复合材料中出现了晶粒粗化现象。随着TiC含量从0 wt%增加到5 wt%,复合材料的力学性能先增加后降低。铸态3 wt%TiC/6061复合材料的维氏硬度、屈服强度、抗拉强度和伸长率分别达到最大值80.7 HV、135 MPa、202 MPa和15.3%。TiC/6061纳米复合材料的强化机制是微观力学强化机制。随着TiC含量的增加,热膨胀系数(CTE)强化起重要作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0c50/11402697/036cf370a7dd/gr1.jpg

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