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藜麦废渣中的皂素分子:探索其表面活性剂、乳化和去污性能。

Saponin Molecules from Quinoa Residues: Exploring Their Surfactant, Emulsifying, and Detergent Properties.

机构信息

Laboratorio de Bioprocesos, Facultad de Ciencias Farmacéuticas, Bioquímicas y Biotecnológicas, Universidad Católica de Santa María-UCSM, Urb. San José s/n-Umacollo, Arequipa 04000, Peru.

Department of Biotechnology, Engineering School of Lorena, University of São Paulo (EEL-USP), Lorena 12602-810, SP, Brazil.

出版信息

Molecules. 2024 Oct 18;29(20):4928. doi: 10.3390/molecules29204928.

Abstract

The indiscriminate use of synthetic surfactants, despite their desirable properties, poses significant environmental risks to ecosystems. This study explores saponins extracted from quinoa () residues as a sustainable alternative. Saponin extract (SE) with 42% purity, obtained through hydrodynamic cavitation and membrane technology, was analyzed to determine its techno-functional properties. The critical micelle concentration (CMC) was 1.2 g/L, reducing the surface tension (ST) from 72.0 mN/m to 50.0 mN/m. The effects of temperature (30-90 °C), pH (2-12), and salinity (10,000-150,000 ppm NaCl) on ST and the emulsification index (EI) were assessed using a Box-Behnken design. Optimized conditions yielded an ST of 49.02 mN/m and an EI of 63%. Given these characteristics, SE was evaluated as a detergent across diverse swatches. This study showcases the attributes of quinoa-derived saponins, highlighting their potential for eco-friendly detergent applications.

摘要

尽管合成表面活性剂具有理想的特性,但不加区分地使用它们会对生态系统造成重大的环境风险。本研究探索了从小麦藜()残渣中提取的皂素,作为一种可持续的替代物。通过水力空化和膜技术获得的纯度为 42%的皂素提取物(SE)经过分析,确定了其技术功能特性。临界胶束浓度(CMC)为 1.2 g/L,将表面张力(ST)从 72.0 mN/m 降低至 50.0 mN/m。采用 Box-Behnken 设计评估了温度(30-90°C)、pH 值(2-12)和盐度(10,000-150,000 ppm NaCl)对 ST 和乳化指数(EI)的影响。在优化条件下,ST 为 49.02 mN/m,EI 为 63%。鉴于这些特性,SE 在各种不同的样本中被评估为一种清洁剂。本研究展示了从小麦藜中提取的皂素的特性,突出了它们在环保型清洁剂应用中的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6392/11510682/c70911b1699c/molecules-29-04928-g001.jpg

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