Department of Civil and Environmental Engineering, University of Illinois Urbana-Champaign, 3221 Newmark Civil Engineering Laboratory, 205 N. Mathews Avenue, Urbana, Illinois 61801, United States.
Department of Civil, Environmental, and Geo- Engineering, University of Minnesota, 500 Pillsbury Drive S.E., Minneapolis, Minnesota 55455, United States.
Environ Sci Technol. 2024 Nov 5;58(44):19651-19665. doi: 10.1021/acs.est.4c05389. Epub 2024 Oct 26.
This study aims to support the prioritization of research and development (R&D) pathways of an anaerobic technology leveraging hydrogel-encapsulated biomass to treat high-strength organic industrial wastewaters, enabling decentralized energy recovery and treatment to reduce organic loading on centralized treatment facilities. To characterize the sustainability implications of early-stage design decisions and to delineate R&D targets, an encapsulated anaerobic process model was developed and coupled with design algorithms for integrated process simulation, techno-economic analysis, and life cycle assessment under uncertainty. Across the design space, a single-stage configuration with passive biogas collection was found to have the greatest potential for financial viability and the lowest life cycle carbon emission. Through robust uncertainty and sensitivity analyses, we found technology performance was driven by a handful of design and technological factors despite uncertainty surrounding many others. Hydraulic retention time and encapsulant volume were identified as the most impactful design decisions for the levelized cost and carbon intensity of chemical oxygen demand (COD) removal. Encapsulant longevity, a technological parameter, was the dominant driver of system sustainability and thus a clear R&D priority. Ultimately, we found encapsulated anaerobic systems with optimized fluidized bed design have significant potential to provide affordable, carbon-negative, and distributed COD removal from high strength organic wastewaters if encapsulant longevity can be maintained at 5 years or above.
本研究旨在支持利用水凝胶包封生物质的厌氧技术的研发 (R&D) 途径的优先级,以处理高强度有机工业废水,实现分散式能源回收和处理,减少有机负荷对集中处理设施的影响。为了描述早期设计决策的可持续性影响,并划定 R&D 目标,开发了一种包封的厌氧过程模型,并与集成过程模拟、技术经济分析和不确定性下的生命周期评估的设计算法耦合。在整个设计空间中,发现具有被动沼气收集的单级配置具有最大的财务可行性和最低的生命周期碳排放潜力。通过稳健的不确定性和敏感性分析,我们发现尽管许多其他因素存在不确定性,但技术性能还是由少数设计和技术因素驱动的。水力停留时间和封装剂体积被确定为水平化成本和化学需氧量 (COD) 去除碳强度的最具影响力的设计决策。作为系统可持续性的主要驱动因素,封装剂的寿命是一个技术参数,因此是明确的 R&D 重点。最终,如果封装剂的寿命可以维持在 5 年或以上,我们发现经过优化的流化床设计的包封厌氧系统具有从高强度有机废水中提供经济实惠、碳中和和分散式 COD 去除的巨大潜力。