Bezerra Pedro H S, Souza-Santos Yves J, Pallone Eliria M J A, Carvalho Rosemary A, Vanin Fernanda M
Food Engineering Department, Faculdade de Zootecnia e Engenharia de Alimentos (USP/FZEA), Multiuser Center for Macromolecule Functionality (CEMFUM), Universidade de São Paulo, Av. Duque de Caxias Norte 225, Pirassununga 13635-900, SP, Brazil.
Biosystems Engineering Department, Faculdade de Zootecnia e Engenharia de Alimentos (USP/FZEA), Multiusuário de Caracterização de Materiais (MULTMAT), Universidade de São Paulo, Av. Duque de Caxias Norte 225, Pirassununga 13635-900, SP, Brazil.
Polymers (Basel). 2024 Nov 30;16(23):3382. doi: 10.3390/polym16233382.
Pollution caused by nonrenewable plastics has driven the use of natural polymers. Similarly, the disposal of food waste still harms the environment. Considering both aspects, this study aimed to evaluate the effect of incorporating orange by-product powder (OBP) as a reinforcing material into sodium alginate films with glycerol. Sodium alginate-based films were produced using glycerol and various concentrations of OBP. The films were characterized in terms of thickness, color, water content, mechanical properties, light transmission, transparency, X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FTIR), contact angle, solubility, swelling, scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The addition of OBP significantly ( < 0.05) reduced the water content of the film from 37.75% ± 5.80a (0-OBP) to 24.49% ± 1.47b (45-OBP). The higher the concentration of OBP, the higher the tensile strength of the films, from 7.99 MPa ± 0.91a (0-OBP) to 18 MPa ± 1.38d (45-OBP), and the higher the hydrophobicity, from 57.60° ± 0.41a (0-OBP) to 70.34° ± 0.98c (45-OBP). From TGA and XRD analyses, it was observed that the incorporation of OBP resulted in less crystalline and more thermally resistant materials. Therefore, this study shows that OBP is a promising reinforcing component for sodium alginate films.
不可再生塑料造成的污染推动了天然聚合物的使用。同样,食物垃圾的处理仍然对环境有害。综合考虑这两个方面,本研究旨在评估将橙皮副产物粉末(OBP)作为增强材料加入含有甘油的海藻酸钠薄膜中的效果。使用甘油和不同浓度的OBP制备了海藻酸钠基薄膜。对薄膜的厚度、颜色、含水量、机械性能、透光率、透明度、X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、接触角、溶解度、溶胀度、扫描电子显微镜(SEM)和热重分析(TGA)进行了表征。OBP的添加显著(<0.05)降低了薄膜的含水量,从37.75%±5.80a(0-OBP)降至24.49%±1.47b(45-OBP)。OBP的浓度越高,薄膜的拉伸强度越高,从7.99MPa±0.91a(0-OBP)增至18MPa±1.38d(45-OBP),疏水性也越高,从57.60°±0.41a(0-OBP)增至70.34°±0.98c(45-OBP)。通过TGA和XRD分析发现,加入OBP后得到的材料结晶度更低、热稳定性更高。因此,本研究表明OBP是海藻酸钠薄膜一种很有前景的增强组分。