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由碳填料增强聚醚醚酮(PEEK)复合材料制成的熔融沉积成型零件在高温下的强度和泊松比。

Strength and Poisson's ratio of fused filament fabrication parts made from carbon filler enhanced PEEK compounds at elevated temperatures.

作者信息

Nyman Leo, Lehto Pauli, Kukko Kirsi, Kestilä Antti, Kallio Esa

机构信息

School of Electrical Engineering, Aalto University, P.O. Box 15500, Aalto, FI-00076, Finland.

Finnish Meteorological Institute, Dynamicum Erik Palménin aukio 1, Helsinki, FI-00560, Finland.

出版信息

Sci Rep. 2024 Dec 30;14(1):31628. doi: 10.1038/s41598-024-80470-7.

Abstract

Engineering plastics are finding widespread applications across a broad temperature spectrum, with additive manufacturing (AM) having now become commonplace for producing aerospace-grade components from polymers. However, there is limited data available on the behavior of plastic AM parts exposed to elevated temperatures. This study focuses on investigating the tensile strength, tensile modulus and Poisson's ratio of parts manufactured using fused filament fabrication (FFF) and polyetheretherketone (PEEK) plastics doped with two additives: short carbon fibers (SCFs) and multi-wall carbon nanotubes (MWCNTs). Tensile test specimens, conforming to the ISO 527 type-1b standard and printed in the XY-plane, were subjected to elevated temperatures (110 °C, 130 °C). After temperature stabilization, a tensile test was conducted to evaluate how elevated temperatures affect the mechanical properties of the parts. The results were compared to tensile test results obtained at room temperature. Additionally, computed micro-tomography was used to determine the porosity of the FFF parts. Furthermore, differential scanning calorimetry measurements were made. The results indicate that exposure to the elevated temperature range used in this work can reduce the tensile strength by 36%. The effects on the tensile modulus and Poisson's ratio were less pronounced. Based on these findings, SCF-PEEK FFF parts demonstrate higher tensile modulus and specific strength compared to plain-PEEK at elevated temperatures (110-130 °C), supporting their use in lightweight aerospace structures.

摘要

工程塑料正在广泛应用于宽广的温度范围,增材制造(AM)现已成为用聚合物生产航空航天级部件的常见方法。然而,关于塑料增材制造部件在高温下的性能数据有限。本研究聚焦于调查使用熔融长丝制造(FFF)和掺杂两种添加剂的聚醚醚酮(PEEK)塑料制造的部件的拉伸强度、拉伸模量和泊松比,这两种添加剂为短碳纤维(SCF)和多壁碳纳米管(MWCNT)。符合ISO 527 1b型标准且在XY平面打印的拉伸测试试样被置于高温(110°C、130°C)下。温度稳定后,进行拉伸测试以评估高温如何影响部件的机械性能。将结果与在室温下获得的拉伸测试结果进行比较。此外,使用计算机断层扫描来确定FFF部件的孔隙率。此外,还进行了差示扫描量热法测量。结果表明,暴露于本工作中使用的高温范围可使拉伸强度降低36%。对拉伸模量和泊松比的影响不太明显。基于这些发现,在高温(110 - 130°C)下,SCF - PEEK FFF部件与纯PEEK相比表现出更高的拉伸模量和比强度,这支持了它们在轻质航空航天结构中的应用。

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