Highlighting Free-Recovery and Work-Generating Shape Memory Effects at 80r-PET Thermoformed Cups.

The paper starts by describing the manufacturing process of cups thermoformed from extruded foils of 80% recycled PET (80r-PET), which comprises heating, hot deep drawing and cooling. The 80r-PET foils were heated up to 120 °C, at heating rates of the order of hundreds °C/min, and deep drawn with multiple punchers, having a depth-to-width ratio exceeding 1:1. After puncher-assisted deformation, the cups were air blown away from the punchers, thus being "frozen" in the deformed state. Due to the high cooling rate, most of the polymer's structure reached a rigid, glassy state, the internal stresses that tended to recover the flat undeformed state were blocked and the polymer remained in a temporary cup form. When heating was applied, glass transition occurred, and the polymer reached a rubbery state and softened. This softening process released the blocked internal stresses and the polymer tended to recover its flat permanent shape. This relative volume contraction quantitatively describes the shape memory effect (SME) which can be obtained either with free recovery (FR-SME) or with work generation (WG-SME) when the cups lifted their bottoms with different loads placed inside them. The paper discusses the results obtained by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), room-temperature tensile failure tests (TENS) and scanning electron microscopy (SEM). The DSC charts emphasized a glass transition, responsible for SME occurrence. The DMA thermograms and the TENS curves revealed that there are slight differences between the storage modulus and the tensile strains of the specimens cut on longitudinal, transversal, or 45° to the film rolling direction. The SEM micrographs enabled to observe structural differences between the specimens cut parallelly and transversally to the film's rolling direction. The thermoformed cups were heated on a special experimental setup, which enabled the determination of FR-SME and WG-SME after applying different maximum temperatures and loads placed into the cups, respectively.