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在广泛温度范围内,对含黄原胶的无泡流体中α-烯烃磺酸盐和十二烷基硫酸盐的比较分析。

A comparative analysis of alpha olefin sulfonate and dodecyl sulfate in aphronic fluid containing xanthan gum in a wide range of temperatures.

作者信息

Riazi Mohsen, Hemmati-Sarapardeh Abdolhossein, Schaffie Mahin, Zabihi Reza, Riazi Masoud

机构信息

Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman, Iran.

Department of Petroleum Engineering, School of Mining and Geosciences, Nazarbayev University, Astana, Kazakhstan.

出版信息

Sci Rep. 2025 Jan 20;15(1):2507. doi: 10.1038/s41598-024-80475-2.

Abstract

Geothermal energy, oil industry, and underground gas storage technology require deep drilling. Although oil-based drilling fluids have been widely used, they cause environmental issues. Environmentally friendly Aphronic fluid has emerged as an alternative to oil-based drilling fluid. Despite various investigations on Aphron's performance, the effect of temperature has not yet been comprehensively studied. In this study, Aphronic fluid was developed with xanthan gum (XG) as a polymer and alpha-olefin sulfonate (AOS) as a surfactant. Furthermore, another Aphronic fluid was developed with xanthan gum (XG) as a polymer and sodium dodecyl sulfate (SDS) as a surfactant. This study evaluates their rheological properties, including shear rate (ranging from 0.1 to 10 s), across a range of temperatures (25 ℃, 49 ℃, 71 ℃, and 93 ℃). Stability testing was conducted at ambient temperature, and rheology tests were performed at various temperatures. It was found that the rheological properties decrease as the temperature increases. An increase in the temperature and shear rate decreases the viscosity of the drilling fluid. AOS demonstrated higher stability and less reduction in rheological properties at elevated temperatures than SDS. This difference can be attributed to SDS's tendency to denature the XG polymer, leading to a notable decrease in viscosity. Maintaining viscosity is crucial for fluid stability and enhancement of rheological properties. Moreover, the best stability was achieved at 1.5 times the critical micelle concentration (CMC). This behavior is consistent with the Gibbs elasticity theory, indicating that the optimal concentration for both AOS and SDS surfactants is 1.5 times the CMC. Deviation from this optimal concentration resulted in decreased system stability. The determination of the CMC value showed a broader region rather than a singular point, potentially confirming the Gibbs-Marangoni theory. The implications of this research underscore the importance of selecting the appropriate Aphronic fluid formula for drilling operations to ensure stability and rheological properties conducive to overcoming reservoir pressure and accurately facilitating the cutting transfer process. This research highlights the need to choose the right Aphronic fluid formula for drilling. Using the right formula helps in drilling to ensure stability and rheological properties conducive to overcoming reservoir pressure and accurately facilitating the cutting transfer process.

摘要

地热能、石油工业和地下储气技术都需要进行深钻孔。尽管油基钻井液已被广泛使用,但它们会引发环境问题。环保型泡沫流体已成为油基钻井液的替代品。尽管对泡沫流体的性能进行了各种研究,但温度的影响尚未得到全面研究。在本研究中,以黄原胶(XG)为聚合物、α-烯烃磺酸盐(AOS)为表面活性剂开发了一种泡沫流体。此外,还以黄原胶(XG)为聚合物、十二烷基硫酸钠(SDS)为表面活性剂开发了另一种泡沫流体。本研究评估了它们在一系列温度(25℃、49℃、71℃和93℃)下的流变特性,包括剪切速率(范围为0.1至10 s)。在环境温度下进行稳定性测试,并在不同温度下进行流变学测试。结果发现,流变特性随温度升高而降低。温度和剪切速率的增加会降低钻井液的粘度。与SDS相比,AOS在高温下表现出更高的稳定性,流变特性降低得更少。这种差异可归因于SDS使XG聚合物变性的倾向,导致粘度显著降低。保持粘度对于流体稳定性和流变特性的增强至关重要。此外,在临界胶束浓度(CMC)的1.5倍时实现了最佳稳定性。这种行为与吉布斯弹性理论一致,表明AOS和SDS表面活性剂的最佳浓度均为CMC的1.5倍。偏离该最佳浓度会导致系统稳定性下降。CMC值的测定显示出一个较宽的区域而非一个单点,这可能证实了吉布斯-马兰戈尼理论。本研究的意义强调了为钻井作业选择合适的泡沫流体配方以确保稳定性和流变特性的重要性,这有利于克服储层压力并准确促进岩屑传递过程。这项研究强调了为钻井选择正确的泡沫流体配方的必要性。使用正确的配方有助于钻井,以确保稳定性和流变特性有利于克服储层压力并准确促进岩屑传递过程。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bafa/11747525/700dad58cc7b/41598_2024_80475_Fig1_HTML.jpg

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