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含高密度粒子的石蜡基复合材料:铅、铋及其氧化物作为γ射线屏蔽材料的实验研究

Paraffin-based composites containing high density particles: lead and bismuth and its' oxides as γ-ray shielding materials: an experimental study.

作者信息

Sobczak Jolanta, Cioch Krzysztof, Żyła Gaweł

机构信息

Doctoral School of the Rzeszów University of Technology, Rzeszów University of Technology, Powstańców Warszawy 12, 35-959, Rzeszów, Poland.

Department of Physics and Medical Engineering, Rzeszów University of Technology, Powstańców Warszawy 6, 35-959, Rzeszów, Poland.

出版信息

Discov Nano. 2025 Feb 12;20(1):33. doi: 10.1186/s11671-025-04203-z.

Abstract

Shielding nano- and microcomposites have emerged as a promising solution in the constantly growing requirements and expectations in the field of radiological protection. The majority of gamma and X-ray shielding nanocomposites are based on polymers due to lightweight, low cost and flexibility as the inviting features in comparison to traditional lead shields. Taking this into consideration, the following study proposes gamma-ray shielding composites characterized by their susceptibility to shape change using the heat and manual pressure. The paraffin-based composites were filled with pure lead and bismuth particles (Bi and Pb, in one mass fraction: 10 wt%) as well as it's oxides: bismuth (III) oxide (BiO) particles and lead (II,IV) oxide particles (PbO) (manufactured in two concentrations: 10 and 50 wt%). Based on experimental studies utilizing Co the half-value layers were calculated approximately 13-14 cm and ca. 9 cm for 10 wt% and 50 wt% filler concentration, respectively. The relatively quick and straightforward manufacturing process, utilizing two commercially available components, allows for the production of a gamma-ray shielding composite featuring a variety of shape choices, facilitating its use in areas where acquiring complex shields remains problematic, or the desired shape development requires repetition of the production process, changes in some of its stages and modification of the composition.

摘要

在放射防护领域不断增长的需求和期望下,屏蔽型纳米和微复合材料已成为一种有前景的解决方案。与传统铅屏蔽相比,大多数伽马射线和X射线屏蔽纳米复合材料基于聚合物,因其具有重量轻、成本低和柔韧性等诱人特性。考虑到这一点,以下研究提出了具有热致和手动压力致形状变化敏感性的伽马射线屏蔽复合材料。石蜡基复合材料填充有纯铅和铋颗粒(Bi和Pb,质量分数为10 wt%)及其氧化物:氧化铋(BiO)颗粒和铅(II,IV)氧化物颗粒(PbO)(以10 wt%和50 wt%两种浓度制造)。基于利用钴的实验研究,对于10 wt%和50 wt%的填料浓度,半值层分别约为13 - 14厘米和约9厘米。利用两种市售成分的相对快速且直接的制造工艺,能够生产具有多种形状选择的伽马射线屏蔽复合材料,便于在获取复杂屏蔽存在问题的区域使用,或者所需形状的开发需要重复生产过程、改变其某些阶段并调整成分的情况下使用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7fe2/11822140/e285451cac0d/11671_2025_4203_Fig1_HTML.jpg

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