Enhanced Photocatalytic Activity of CQDs-Modified Layered g-CN/Flower-like ZnO Heterojunction for Efficient Degradation of Ciprofloxacin.

Photocatalytic degradation has the advantages of high efficiency and stability compared with traditional antibiotic treatment. Therefore, the development of efficient and stable photocatalysts is essential for antibiotic degradation in water treatment. In this study, layered g-CN/flower-like ZnO heterojunction loaded with different amounts of CQDs (CCNZO (x = 1, 2, 3, 4)) were precisely synthesized at room temperature. The as-prepared photocatalyst showed enhanced performance in degrading ciprofloxacin (CIP). The heterojunction with CQDs loaded at 3 wt% (CCNZO) achieved a 91.0% removal rate of CIP at 120 min under a sunlight simulator illumination, and the photodegradation reaction data were consistent with the first-order kinetic model. In addition, cycling experiments confirmed that the CCNZO heterojunction had good reusability and photocatalytic stability after four cycles. According to the experimental results, superoxide radical (•O) was the main active species involved in CIP degradation. Furthermore, CCNZO was found to conform to a type II electron transfer pathway. Finally, the possible degradation pathways of CIP were analyzed. This work may provide an effective strategy for the removal of various antibiotics in water treatment.