Wang Bo, Zhang Qingtao, Liu Caisen, Wang Zhixin, Zhang Yunjian
College of Civil Engineering and Architecture, Shandong University of Aeronautics, Binzhou 256600, China.
College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China.
Langmuir. 2025 Apr 29;41(16):10188-10196. doi: 10.1021/acs.langmuir.4c05072. Epub 2025 Apr 15.
This study addresses the issue of varying the wetting effects of surfactants in coal dust control. Utilizing low-field nuclear magnetic resonance (LF-NMR) experiments and molecular dynamics (MD) simulations, it reveals the microscopic wetting mechanism of nonionic surfactant fatty alcohol polyoxyethylene ether (JFCS) on different coal ranks. The results indicate that JFCS can reduce the attractive forces between molecules on the coal surface, promoting the diffusion of water molecules at the coal interface. The wetting effect of JFCS on lignite is superior to that on bituminous coal. The wetting range and diffusion rate of water molecules in the surfactant system were obtained, elucidating the microscopic wetting mechanism and influencing the laws of different coal ranks under the action of surfactants. This provides excellent theoretical guidance for coal seam water injection dust prevention, improves the effectiveness and pertinence of mine dust control, and contributes to the improvement of cleaner production levels in mines.
本研究探讨了表面活性剂在煤尘控制中润湿性变化的问题。通过低场核磁共振(LF-NMR)实验和分子动力学(MD)模拟,揭示了非离子表面活性剂脂肪醇聚氧乙烯醚(JFCS)对不同煤阶的微观润湿机理。结果表明,JFCS可降低煤表面分子间的吸引力,促进水分子在煤界面的扩散。JFCS对褐煤的润湿效果优于烟煤。得到了表面活性剂体系中水分子的润湿范围和扩散速率,阐明了微观润湿机理以及表面活性剂作用下不同煤阶的影响规律。这为煤层注水防尘提供了良好的理论指导,提高了矿井粉尘治理的有效性和针对性,有助于提升矿井清洁生产水平。