du Toit Nadine, Müller-Nedebock Kristian K
Department of Physics, Stellenbosch University, Stellenbosch, 7602, South Africa.
National Institute for Theoretical and Computational Sciences, Stellenbosch, 7602, South Africa.
Eur Phys J E Soft Matter. 2025 May 24;48(4-5):27. doi: 10.1140/epje/s10189-025-00489-0.
A novel field theoretical approach towards modelling dynamic networking in complex systems is presented. An equilibrium networking formalism which utilises Gaussian fields is adapted to model the dynamics of particles that can bind and unbind from one another. Here, networking refers to the introduction of instantaneous co-localisation constraints and does not necessitate the formation of a well-defined transient or persistent network. By combining this formalism with Martin-Siggia-Rose generating functionals, a weighted generating functional for the networked system is obtained. The networking formalism introduces spatial and temporal constraints into the Langevin dynamics, via statistical weights, thereby accounting for all possible configurations in which particles can be networked to one another. A simple example of Brownian particles which can bind and unbind from one another demonstrates the tool and that this leads to results for physical quantities in a collective description. Applying the networking formalism to model the dynamics of cross-linking polymers in a mixture, we can calculate the average number of networking instances. As expected, the dynamic structure factors for each type of polymer show that the system collapses once networking is introduced, but that the addition of a repulsive time-dependent potential above a minimum strength prevents this. The examples presented in this paper indicate that this novel approach towards modelling dynamic networking could be applied to a range of synthetic and biological systems to obtain theoretical predictions for experimentally verifiable quantities.
提出了一种用于对复杂系统中的动态网络进行建模的新颖场论方法。一种利用高斯场的平衡网络形式主义被用于对能够相互结合和解离的粒子动力学进行建模。在此,网络指的是引入瞬时共定位约束,并不一定需要形成定义明确的瞬态或持久网络。通过将这种形式主义与马丁 - 西格西亚 - 罗斯生成泛函相结合,得到了网络化系统的加权生成泛函。网络形式主义通过统计权重将空间和时间约束引入朗之万动力学,从而考虑了粒子相互网络化的所有可能构型。一个简单的能够相互结合和解离的布朗粒子示例展示了该工具,并且这在集体描述中得出了物理量的结果。将网络形式主义应用于对混合物中交联聚合物的动力学进行建模,我们可以计算网络实例的平均数。正如预期的那样,每种聚合物的动态结构因子表明,一旦引入网络,系统就会崩溃,但在最小强度之上添加一个随时间变化的排斥势可以防止这种情况。本文给出的示例表明,这种用于对动态网络进行建模的新颖方法可应用于一系列合成和生物系统,以获得可通过实验验证的量的理论预测。