Slemnik Mojca
Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova Ulica 17, SI-2000 Maribor, Slovenia.
Materials (Basel). 2025 May 12;18(10):2243. doi: 10.3390/ma18102243.
Titanium and its alloys, as well as stainless steel, are commonly used materials for implants in the human body due to their excellent biocompatibility, corrosion resistance, and mechanical properties. However, the long-term performance of these materials in the oral cavity can be affected by the complex oral environment, including the ingestion of food, beverages, and oral hygiene products, leading to the presence of various ions, pH fluctuations, and inflammatory processes. In this study, the corrosion properties of two biocompatible materials, Ti6Al4V and AISI 316L stainless steel, are investigated under varying oral inflammatory conditions. Using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), SEM, and EDS analysis, the corrosion behaviour of both materials was analysed in environments simulating mild and severe inflammation. Results indicate that Ti6Al4V exhibits superior corrosion resistance at low HO concentrations mimicking mild inflammation, with significantly lower corrosion rates compared to AISI 316L. However, at higher HO concentrations, which correspond to severe inflammation, AISI 316L shows better resistance despite its susceptibility to pitting corrosion. Both alloys show reduced passivation after 72 h, with corrosion products accumulating on the surface after 96 h, contributing to repassivation. These results emphasise the need for individualized material selection in dental applications based on a patient's susceptibility to oral inflammation.
钛及其合金以及不锈钢,由于其优异的生物相容性、耐腐蚀性和机械性能,是人体植入物常用的材料。然而,这些材料在口腔中的长期性能会受到复杂口腔环境的影响,包括食物、饮料和口腔卫生用品的摄入,从而导致各种离子的存在、pH值波动和炎症过程。在本研究中,研究了两种生物相容性材料Ti6Al4V和AISI 316L不锈钢在不同口腔炎症条件下的腐蚀性能。使用动电位极化、电化学阻抗谱(EIS)、扫描电子显微镜(SEM)和能谱分析(EDS),分析了两种材料在模拟轻度和重度炎症环境中的腐蚀行为。结果表明,在模拟轻度炎症的低过氧化氢浓度下,Ti6Al4V表现出优异的耐腐蚀性,与AISI 316L相比,腐蚀速率显著更低。然而,在对应于重度炎症的较高过氧化氢浓度下,尽管AISI 316L易发生点蚀,但它表现出更好的耐腐蚀性。两种合金在72小时后钝化性能降低,96小时后表面有腐蚀产物堆积,有助于再钝化。这些结果强调了在牙科应用中,需要根据患者对口腔炎症的易感性进行个性化材料选择。