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下一代环保型混合空气净化器:用于增强生物气溶胶去除的Ag/TiO/PLA生物膜

Next-Generation Eco-Friendly Hybrid Air Purifier: Ag/TiO/PLA Biofilm for Enhanced Bioaerosols Removal.

作者信息

Chotigawin Rotruedee, Kandasamy Bhuvaneswari, Asa Paradee, Semangoen Tistaya, Ajawatanawong Pravech, Phibanchon Sarun, Pahasup-Anan Taddao, Wongcharee Surachai, Suwannahong Kowit

机构信息

Faculty of Public Health, Burapha University, Chonburi 20131, Thailand.

Department of Civil Engineering, Faculty of Engineering, Rajamangala University of Technology Thanyaburi, Pathum Thani 12110, Thailand.

出版信息

Int J Mol Sci. 2025 May 10;26(10):4584. doi: 10.3390/ijms26104584.

Abstract

Indoor air pollution poses a significant public health risk, particularly in urban areas, where PM2.5 and airborne contaminants contribute to respiratory diseases. In Thailand, including Chonburi Province, PM2.5 levels frequently exceed safety thresholds, underscoring the urgent need for effective mitigation strategies. To address this challenge, we developed a hybrid air purification system incorporating a bioplastic-based photocatalytic film of polylactic acid (PLA) embedded with titanium dioxide (TiO) nanoparticles. For optimization, PLA films were functionalized with varying TiO concentrations and characterized using SEM, FTIR, TGDTA, and UV-Vis. spectroscopy. A 5 wt% TiO loading was identified as optimal and further enhanced with silver (Ag) nanoparticles to boost photocatalytic efficiency. The Ag/TiO/PLA biofilm was fabricated via a compound pellet formulation process followed by blown film extrusion. Various compositions, with and without Ag, were systematically evaluated for photocatalytic performance. The novel customized hybrid air purifier developed in this study is designed to enhance indoor air purification efficiency by integrating Ag/TiO/PLA biofilms into a controlled oxidation system. The air purification efficacy of the developed biofilm was evaluated through a controlled study on () removal under different treatment conditions: control, adsorption, photolysis, and photocatalytic oxidation. The impact of light intensity on photocatalytic efficiency was also examined. The photocatalytic oxidation of was subjected to the first-order kinetic evaluation through mathematical modeling. Results demonstrated that the Ag/TiO/PLA biofilm significantly enhances indoor air purification, providing a sustainable, scalable, and energy-efficient solution for microbial decontamination and pollutant removal. This innovative approach outperforms conventional adsorption, adsorption and photocatalytic oxidation systems, offering a promising pathway for improved indoor air quality.

摘要

室内空气污染对公众健康构成重大风险,尤其是在城市地区,细颗粒物(PM2.5)和空气传播污染物会导致呼吸道疾病。在泰国,包括春武里府在内,PM2.5水平经常超过安全阈值,凸显了制定有效缓解策略的迫切需求。为应对这一挑战,我们开发了一种混合空气净化系统,该系统包含一种基于生物塑料的光催化薄膜,该薄膜由聚乳酸(PLA)制成,并嵌入了二氧化钛(TiO₂)纳米颗粒。为了进行优化,对PLA薄膜进行了不同TiO₂浓度的功能化处理,并使用扫描电子显微镜(SEM)、傅里叶变换红外光谱(FTIR)、热重差热分析(TGDTA)和紫外可见光谱进行了表征。确定5 wt%的TiO₂负载量为最佳,并通过银(Ag)纳米颗粒进一步增强以提高光催化效率。通过复合粒料配方工艺,然后进行吹膜挤出,制备了Ag/TiO₂/PLA生物膜。系统评估了有无Ag的各种组合物的光催化性能。本研究开发的新型定制混合空气净化器旨在通过将Ag/TiO₂/PLA生物膜集成到受控氧化系统中来提高室内空气净化效率。通过在不同处理条件下(对照、吸附、光解和光催化氧化)对()去除的对照研究,评估了所开发生物膜的空气净化效果。还研究了光强度对光催化效率的影响。通过数学建模对()的光催化氧化进行了一级动力学评估。结果表明,Ag/TiO₂/PLA生物膜显著提高了室内空气净化效果,为微生物去污和污染物去除提供了一种可持续、可扩展且节能的解决方案。这种创新方法优于传统的吸附、吸附和光催化氧化系统,为改善室内空气质量提供了一条有前景的途径。

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