（η-三亚甲基甲烷）（1,1,1-三-{[双-（4-甲氧基苯基）膦基]甲基}乙烷）钌（II）二乙醚半溶剂化物
(η-Tri-methyl-ene-methane)(1,1,1-tris-{[bis-(4-meth-oxy-phen-yl)phosphan-yl]meth-yl}ethane)ruthenium(II) diethyl ether hemisolvate.
作者信息
Stein Carolin A M, Alberico Elisabetta, Spannenberg Anke, Beller Matthias, Junge Henrik
机构信息
Leibniz-Institut für Katalyse e V Albert-Einstein-Str 29a 18059 Rostock Germany.
Istituto di Chimica Biomolecolare, CNR, tr. La Crucca 3, 07100 Sassari, Italy.
出版信息
IUCrdata. 2025 Jun 17;10(Pt 6):x250524. doi: 10.1107/S2414314625005243. eCollection 2025 Jun.
The title compound, [Ru(CHOP)(CH)]·0.5CHO, consists of an Ru atom coordinated by 1,1,1-tris-{[bis-(4-meth-oxy-phen-yl)phosphan-yl]meth-yl}ethane in κ-coordination mode and an η-coordinating tri-methyl-ene-methane ligand. The complex mol-ecule is co-crystallized with a diethyl ether solvent mol-ecule. A half diethyl ether mol-ecule was considered, whereas additional disordered solvent mol-ecules were removed from the diffraction data with the SQUEEZE procedure in [Spek (2015 ▸). . C, 9-18].
标题化合物[Ru(CHOP)(CH)]·0.5CHO由一个以κ配位模式与1,1,1-三-{[双-(4-甲氧基苯基)膦基]甲基}乙烷配位的Ru原子和一个η配位的三亚甲基甲烷配体组成。该配合物分子与一个二乙醚溶剂分子共结晶。考虑了半个二乙醚分子，而额外的无序溶剂分子则通过[Spek(2015 ▸).. C, 9-18]中的SQUEEZE程序从衍射数据中去除。
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