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（η-三亚甲基甲烷）（1,1,1-三-{[双-（4-甲氧基苯基）膦基]甲基}乙烷）钌（II）二乙醚半溶剂化物

(η-Tri-methyl-ene-methane)(1,1,1-tris-{[bis-(4-meth-oxy-phen-yl)phosphan-yl]meth-yl}ethane)ruthenium(II) diethyl ether hemisolvate.

作者信息

Stein Carolin A M, Alberico Elisabetta, Spannenberg Anke, Beller Matthias, Junge Henrik

机构信息

Leibniz-Institut für Katalyse e V Albert-Einstein-Str 29a 18059 Rostock Germany.

Istituto di Chimica Biomolecolare, CNR, tr. La Crucca 3, 07100 Sassari, Italy.

出版信息

IUCrdata. 2025 Jun 17;10(Pt 6):x250524. doi: 10.1107/S2414314625005243. eCollection 2025 Jun.

DOI:10.1107/S2414314625005243
PMID:40630058
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12230594/
Abstract

The title compound, [Ru(CHOP)(CH)]·0.5CHO, consists of an Ru atom coordinated by 1,1,1-tris-{[bis-(4-meth-oxy-phen-yl)phosphan-yl]meth-yl}ethane in κ-coordination mode and an η-coordinating tri-methyl-ene-methane ligand. The complex mol-ecule is co-crystallized with a diethyl ether solvent mol-ecule. A half diethyl ether mol-ecule was considered, whereas additional disordered solvent mol-ecules were removed from the diffraction data with the SQUEEZE procedure in [Spek (2015 ▸). . C, 9-18].

摘要

标题化合物[Ru(CHOP)(CH)]·0.5CHO由一个以κ配位模式与1,1,1-三-{[双-(4-甲氧基苯基)膦基]甲基}乙烷配位的Ru原子和一个η配位的三亚甲基甲烷配体组成。该配合物分子与一个二乙醚溶剂分子共结晶。考虑了半个二乙醚分子，而额外的无序溶剂分子则通过[Spek(2015 ▸).. C, 9-18]中的SQUEEZE程序从衍射数据中去除。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f065/12230594/cd9316072b14/x-10-x250524-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f065/12230594/73cb15cf40fb/x-10-x250524-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f065/12230594/cd9316072b14/x-10-x250524-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f065/12230594/73cb15cf40fb/x-10-x250524-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f065/12230594/cd9316072b14/x-10-x250524-fig2.jpg

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