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水溶液中的重力偏向离子迁移。

Gravitation-biased ion migration in aqueous solutions.

作者信息

Im Jooyoung, Santamarina J Carlos

机构信息

Physical Science and Engineering, King Abdullah University of Science and Technology KAUST, Thuwal, 23955, Saudi Arabia.

School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA, 30332, USA.

出版信息

Sci Rep. 2025 Jul 25;15(1):27026. doi: 10.1038/s41598-025-12089-1.

Abstract

The gravity-biased drift of hydrated ions is assumed negligible and therefore disregarded in analysis and design. In this study, we reassess the impact of gravity on hydrated ion migration in aqueous solutions by subjecting six chloride salt solutions to controlled centrifugal acceleration across varying flight durations. The resulting data show that ion migration depends on both g-level and duration, providing clear evidence of gravitational bias. Based on the measured mobilities, gravity-induced effects should not be overlooked in systems extending over several meters or operating on century-long timescales. Recognizing gravity-driven migration has the potential to shift design paradigms, from industrial processes to the geological storage of nuclear waste.

摘要

水合离子的重力偏向漂移被认为可忽略不计,因此在分析和设计中不予考虑。在本研究中,我们通过对六种氯化物盐溶液在不同飞行持续时间内施加可控的离心加速度,重新评估重力对水溶液中水合离子迁移的影响。所得数据表明,离子迁移取决于重力水平和持续时间,这为重力偏向提供了明确证据。基于测得的迁移率,在延伸数米或运行长达百年时间尺度的系统中,重力引起的效应不应被忽视。认识到重力驱动的迁移有可能改变设计范式,从工业过程到核废料的地质储存。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60b5/12289957/af6b440fc38a/41598_2025_12089_Fig1_HTML.jpg

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