Comparing the Accuracy of Soil Moisture Estimates Derived from Bulk and Energy-Resolved Gamma Radiation Measurements.

Monitoring soil moisture (SM) using permanently installed gamma radiation (GR) detectors is a promising non-invasive method based on the inverse relationship between SM and soil-emitted GR. In a previous study, we successfully estimated SM from environmental gamma radiation (EGR) measured by a low-cost counter-tube detector. Since this detector type provides a bulk GR response across a wide energy range, EGR signals are influenced by several confounding factors, e.g., soil radon emanation, biomass. To what extent these confounding factors deteriorate the accuracy of SM estimates obtained from EGR is not fully understood. Therefore, the aim of this study was to compare the accuracy of SM estimates from EGR with those from reference K GR (1460 keV) measurements which are much less influenced by these factors. For this, a Geiger-Mueller counter (G-M), which is commonly used for EGR monitoring, and a gamma spectrometer were installed side by side in an agricultural field equipped with in situ sensors to measure reference SM and a meteorological station. The EGR and spectrometry-based K measurements were related to reference SM using a functional relationship derived from theory. We found that daily SM can be predicted with an RMSE of 3.39 vol. % from K using the theoretical value of = 1.11 obtained from the effective ratio of GR mass attenuation coefficients for the water and solid phase. A lower accuracy was achieved for the EGR measurements (RMSE = 6.90 vol. %). Wavelet coherence analysis revealed that the EGR measurements were influenced by radon-induced noise in winter. Additionally, biomass shielding had a stronger impact on EGR than on K GR estimates of SM during summer. In summary, our study provides a better understanding on the lower prediction accuracy of EGR and suggests that correcting for biomass can improve SM estimation from the bulk EGR data of operational radioactivity monitoring networks.