Hariram V, Sathishbabu R, John J Godwin, Kailiappan Nandagopal, Vijayakumar K, Kumar E Sangeeth, Priya K Kamakshi
Department of Mechanical Engineering, Hindustan Institute of Technology and Science, Padur, Chennai, Tamil Nadu, India.
Department of Mechanical Engineering, VSB College of Engineering Technical Campus, Coimbatore, Tamil Nadu, India.
Sci Rep. 2025 Aug 19;15(1):30372. doi: 10.1038/s41598-025-16285-x.
Energy resource sustainability has been of critical concern as a result of unlimited energy demand worldwide. In this research work, extraction of the alternate fuel for diesel (i.e., biodiesel) from the source Dunaliella salina, which is a greenish microalga with higher lipid content comparatively, is being primarily addressed. Cultivation was provided under nitrogen starvation, f/2 trace-element supplemented, nutrient medium supplemented with vitamins and CO. Ultrasonic extraction method at 50 Hz yielded 645 ml of Dunaliella salina bio-oil in repeated batches. One stage base catalysed process of transesterification with 1:8 mol ratio of methanol to oil, 0.6% w/w NaOH catalyst, reaction temperature of 50 °C and reaction time of 120 min yielded 612 ml Dunaliella salina biodiesel in 6 batches with 94.8% efficiency in transesterification. Physio-chemical properties of the produced biodiesel were determined to be as per ASTM specifications. Additional GCMS, NMR and FTIR spectroscopic study of the derived biodiesel established its suitability for CI engine. Dunaliella salina biodiesel blend at 20% volume ratio was compared with diesel on combustion, emission and performance characteristics of Kirloskar 240 PE test engine. Additional supplementation of Hydrogen by DuSaBD20 at 3 LPM, 6 LPM and 9 LPM had pronounced impact on the engine performance with remarkable CO reduction and UBHC and a slight increase in engine NOx was observed. Additionally, the study of cost of operation on H induction was also investigated.
由于全球能源需求无限,能源资源的可持续性一直备受关注。在这项研究工作中,主要探讨了从杜氏盐藻中提取柴油替代燃料(即生物柴油),杜氏盐藻是一种脂质含量相对较高的绿色微藻。在氮饥饿、添加f/2微量元素、添加维生素和CO的营养培养基条件下进行培养。50Hz的超声提取方法在重复批次中得到了645ml杜氏盐藻生物油。在甲醇与油的摩尔比为1:8、NaOH催化剂用量为0.6%w/w、反应温度为50°C、反应时间为120min的条件下,通过一步碱催化酯交换过程,6个批次得到了612ml杜氏盐藻生物柴油,酯交换效率为94.8%。所生产生物柴油的理化性质经测定符合ASTM规范。对衍生生物柴油进行的额外气相色谱-质谱联用、核磁共振和傅里叶变换红外光谱研究证实了其适用于CI发动机。将体积比为20%的杜氏盐藻生物柴油混合物与柴油在Kirloskar 240 PE测试发动机的燃烧、排放和性能特性方面进行了比较。杜氏盐藻生物柴油20(DuSaBD20)分别以3LPM、6LPM和9LPM的速率额外补充氢气,对发动机性能产生了显著影响,CO显著减少,未燃碳氢化合物(UBHC)减少,同时观察到发动机氮氧化物(NOx)略有增加。此外,还研究了氢气引入情况下的运行成本。