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分子水平上的镜像对称破缺。

Mirror symmetry breaking at the molecular level.

作者信息

Avetisov V, Goldanskii V

机构信息

N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia.

出版信息

Proc Natl Acad Sci U S A. 1996 Oct 15;93(21):11435-42. doi: 10.1073/pnas.93.21.11435.

Abstract

Reasoning from two basic principles of molecular physics, P invariance of electromagnetic interaction and the second law of thermodynamics, one would conclude that mirror symmetry retained in the world of chiral molecules. This inference is fully consistent with what is observed in inorganic nature. However, in the bioorganic world, the reverse is true. Mirror symmetry there is definitely broken. Is it possible to account for this phenomenon without going beyond conventional concepts of the kinetics of enantioselective processes? This study is an attempt to survey all existing hypotheses containing this phenomenon.

摘要

从分子物理学的两个基本原理——电磁相互作用的P不变性和热力学第二定律进行推理,人们会得出结论,镜像对称在手性分子世界中得以保留。这一推断与在无机自然界中观察到的现象完全一致。然而,在生物有机世界中,情况却恰恰相反。那里的镜像对称肯定被打破了。是否有可能在不超越对映选择性过程动力学的传统概念的情况下解释这一现象呢?本研究旨在全面审视所有包含这一现象的现有假说。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e120/38075/6cad92e4ab7a/pnas01525-0162-a.jpg

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