豆粕壳对水溶液中直接染料和酸性染料吸附的平衡及动力学研究

Equilibrium and kinetics studies for the adsorption of direct and acid dyes from aqueous solution by soy meal hull.

作者信息

Arami Mokhtar, Limaee Nargess Yousefi, Mahmoodi Niyaz Mohammad, Tabrizi Nooshin Salman

机构信息

Environmental Science and Engineering Department, Iran Color Research Center, Tehran, Iran.

出版信息

J Hazard Mater. 2006 Jul 31;135(1-3):171-9. doi: 10.1016/j.jhazmat.2005.11.044. Epub 2006 Jan 24.

Abstract

This paper deals with the application of Soy Meal Hull (SMH), an agricultural by-product, for the removal of direct and acid dyes from aqueous solutions. Four textile dyes, C.I. Direct red 80 (DR80), C.I. Direct red 81 (DR81), C.I. Acid blue 92 (AB92) and C.I. Acid red 14 (AR14) were used as model compounds. Physical characteristics of SMH such as surface area, Fourier transform infra-red (FTIR) and scanning electron microscopy (SEM) were obtained. The surface area of SMH was found to be 0.7623 m(2)/g and the presence of functional groups such as hydroxyl, amine and carbonyl groups were detected. The effect of initial dye concentration, pH, contact time and SMH doses were elucidated at 20+/-1 degrees C. Results show that the pH value of 2 is favorable for the adsorption of all four dyes. The data evaluated for compliance with the Langmuir, Freundlich and BET isotherm models. It was found that data for DR80 and DR81 fitted well with Langmuir isotherm, for AB92, BET isotherm is preferred, while for AR14, the Freundlich isotherm is the most applicable. The adsorption capacities of SMH for DR80, DR81, AB92 and AR14 were, 178.57, 120.48, 114.94 and 109.89 mg/g of adsorbent, respectively. Also, adsorption kinetics of dyes was studied and the rates of sorption were found to conform to pseudo-second order kinetics with good correlation (R(2)> or =0.9977). Maximum desorption of > or =99.8% was achieved for DR80, DR81 and AB92 and 86% for AR14 in aqueous solution at pH 10. Based on the data of present investigation, one could conclude that the SMH being a natural, eco-friendly and low-cost adsorbent with relatively large adsorption capacity might be a suitable local alternative for elimination of dyes from colored aqueous solutions.

摘要

本文探讨了农业副产品豆粕壳(SMH)在去除水溶液中直接染料和酸性染料方面的应用。选用了四种纺织染料,即C.I.直接红80(DR80)、C.I.直接红81(DR81)、C.I.酸性蓝92(AB92)和C.I.酸性红14(AR14)作为模型化合物。测定了SMH的物理特性,如表面积、傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)。发现SMH的表面积为0.7623 m²/g,并检测到其存在羟基、胺基和羰基等官能团。在20±1℃下,研究了初始染料浓度、pH值、接触时间和SMH用量的影响。结果表明,pH值为2有利于所有四种染料的吸附。对数据进行评估,以确定其是否符合朗缪尔、弗伦德里希和BET等温线模型。结果发现,DR80和DR81的数据与朗缪尔等温线拟合良好,AB92的数据更适合BET等温线,而AR14的数据最适合弗伦德里希等温线。SMH对DR80、DR81、AB92和AR14的吸附容量分别为178.57、120.48、114.94和109.89 mg/g吸附剂。此外,还研究了染料的吸附动力学,发现吸附速率符合伪二级动力学,相关性良好(R²≥0.9977)。在pH值为10的水溶液中,DR80、DR81和AB92的最大解吸率≥99.8%,AR14的最大解吸率为86%。基于本研究的数据,可以得出结论,SMH作为一种天然、环保且低成本的吸附剂,具有相对较大的吸附容量,可能是从有色水溶液中去除染料的合适本地替代品。

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