水热重结晶磁铁矿晶体的磁性。
Magnetic properties of hydrothermally recrystallized magnetite crystals.
出版信息
Science. 1987 Jun 5;236(4806):1287-90. doi: 10.1126/science.236.4806.1287.
The discrepancy between the magnetic hysteresis properties of magnetite crystals that are precipitated from solution (<0.3 micrometer) and of crushed sifted grains (>0.3 micrometer) is not an inherent property of magnetite but is caused by the highly stressed state of crushed material and by adhering finer fragments. The size trends of magnetic properties exhibited by submicrometer-size precipitated grains continue in the size range from 1 micrometer to 1 millimeter in a set of hydrothermally recrystallized magnetite crystals. Coercive forces of these narrowly sized crystals follow a power law over a wide size range (0.1 micrometer to 1 millimeter) as predicted by theory. Dislocation etch pits show similar dislocation densities for hydrothermally grown (3 x 10(10) meter (-2)) and natural (1 x 10(10) meter(-2)) magnetite crystals. Hysteresis parameters of hydrothermally grown crystals are similar to those of natural crystals but are about one-fifth of those for crushed grains.
从溶液中沉淀出来的(<0.3 微米)和粉碎过筛的(<0.3 微米)磁铁矿晶体的磁滞特性之间的差异不是磁铁矿的固有特性,而是由粉碎材料的高应状态和附着的更细的碎片引起的。在一组水热重结晶的磁铁矿晶体中,亚微米大小的沉淀颗粒表现出的磁性能的尺寸趋势在从 1 微米到 1 毫米的尺寸范围内继续存在。这些窄尺寸晶体的矫顽力遵循幂律,在很宽的尺寸范围内(0.1 微米到 1 毫米),这与理论预测一致。位错腐蚀坑显示出类似的位错密度,对于水热生长的(3 x 10(10) 米(-2))和天然的(1 x 10(10) 米(-2))磁铁矿晶体。水热生长晶体的磁滞参数与天然晶体相似,但约为粉碎颗粒的五分之一。