通过化学氧化还原作用快速、可逆地制备尺寸可控的银纳米板。
Rapid, reversible preparation of size-controllable silver nanoplates by chemical redox.
机构信息
Department of Chemical Engineering, Kwangwoon University, Seoul 139-701, Korea.
出版信息
Langmuir. 2010 Jul 20;26(14):11621-3. doi: 10.1021/la1016627.
Citrate-stabilized silver nanoplates (AgNPs) were prepared using a seed-mediated growth method. The AgNP shape and size were controlled using potassium permanganate (KMnO(4)) as an oxidant and ascorbic acid (AA) as a reductant. Using KMnO(4), 42 nm nanoplates were changed to 22.9 nm nanodisks because of the release of silver ions. Using AA, the oxidized AgNPs were resynthesized to their initial plate form. These results are similar to those obtained using photoinduced shape control of silver nanoparticles; however, the chemical oxidation/reduction method can control the shape of AgNPs, both quantitatively and reversibly. In addition, because of redox-related visible spectral changes, solution color varies with AgNPs size. That feature may be useful in various applications.
采用种子生长法制备了柠檬酸钠稳定的银纳米片(AgNPs)。通过使用高锰酸钾(KMnO4)作为氧化剂和抗坏血酸(AA)作为还原剂来控制 AgNP 的形状和尺寸。由于银离子的释放,使用 KMnO4 将 42nm 的纳米片改变为 22.9nm 的纳米盘。使用 AA,氧化的 AgNPs 被重新合成到其初始的板状形式。这些结果与使用银纳米粒子的光诱导形状控制得到的结果相似;然而,化学氧化/还原法可以定量且可逆地控制 AgNPs 的形状。此外,由于与氧化还原相关的可见光谱变化,溶液颜色随 AgNPs 尺寸而变化。该特性在各种应用中可能很有用。