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混合阳离子甲脒-甲基铵碘化铅钙钛矿[HC(NH)][CHNH]PbI纳米棒的载流子衰减特性

Carrier Decay Properties of Mixed Cation Formamidinium-Methylammonium Lead Iodide Perovskite [HC(NH)][CHNH]PbI Nanorods.

作者信息

Dai Jun, Fu Yongping, Manger Lydia H, Rea Morgan T, Hwang Leekyoung, Goldsmith Randall H, Jin Song

机构信息

Department of Chemistry, University of Wisconsin-Madison , Madison, Wisconsin 53705, United States.

Department of Physics, Jiangsu University of Science and Technology , Zhenjiang 212003, China.

出版信息

J Phys Chem Lett. 2016 Dec 15;7(24):5036-5043. doi: 10.1021/acs.jpclett.6b01958. Epub 2016 Nov 29.

Abstract

Organic-inorganic lead iodide perovskites are efficient materials for photovoltaics and light-emitting diodes. We report carrier decay dynamics of nanorods of mixed cation formamidinium and methylammonium lead iodide perovskites [HC(NH)][CHNH]PbI (FAMAPbI) synthesized through a simple solution method. The structure and FA/MA composition ratio of the single-crystal FAMAPbI nanorods are fully characterized, which shows that the mixed cation FAMAPbI nanorods are stabilized in the perovskite structure. The photoluminescence (PL) emission from FAMAPbI nanorods continuously shifts from 821 to 782 nm as the MA ratio (x) increases from 0 to 1 and is shown to be inhomogeneously broadened. Time-resolved PL from individual FAMAPbI nanorods demonstrates that lifetimes of mixed cation FAMAPbI nanorods are longer than those of the pure FAPbI or MAPbI nanorods, and the FAMAPbI displays the longest average PL lifetime of about 2 μs. These results suggest that mixed cation FAMAPbI perovskites are promising for high-efficiency photovoltaics and other optoelectronic applications.

摘要

有机-无机碘化铅钙钛矿是用于光伏和发光二极管的高效材料。我们报告了通过简单溶液法合成的混合阳离子甲脒和甲基铵碘化铅钙钛矿[HC(NH)][CHNH]PbI(FAMAPbI)纳米棒的载流子衰减动力学。对单晶FAMAPbI纳米棒的结构和FA/MA组成比进行了全面表征,结果表明混合阳离子FAMAPbI纳米棒在钙钛矿结构中是稳定的。随着MA比例(x)从0增加到1,FAMAPbI纳米棒的光致发光(PL)发射从821 nm连续移至782 nm,并且显示出非均匀展宽。单个FAMAPbI纳米棒的时间分辨PL表明,混合阳离子FAMAPbI纳米棒的寿命比纯FAPbI或MAPbI纳米棒的寿命长,并且FAMAPbI显示出约2 μs的最长平均PL寿命。这些结果表明,混合阳离子FAMAPbI钙钛矿在高效光伏和其他光电子应用方面具有潜力。

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