以轻质芳烃石脑油为添加剂的离子液体电解质中稳健的铝电沉积

Robust Aluminum Electrodeposition from Iionic Liquid Electrolytes Containing Light Aromatic Naphta as Additive.

作者信息

Guinea Elena, Salicio-Paz Asier, Iriarte Aitor, Grande Hans-Jürgen, Medina Estíbaliz, García-Lecina Eva

机构信息

CIDETEC Parque Científico y Tecnológico de Gipuzkoa P° Miramón, 196 20014 Donostia-San Sebastián Spain.

MTC - Maier Technology Centre Polígono Industrial Arabieta B° Kanpantxu S/N 48320 Ajangiz-Bizkaia Spain.

出版信息

ChemistryOpen. 2019 Aug 6;8(8):1094-1099. doi: 10.1002/open.201900183. eCollection 2019 Aug.

Abstract

Aluminum electrodeposition can be carried out from several ionic liquid electrolyte formulations. Nevertheless, this plating process has not been industrialized so far because of the durability of the electrolytes and because the Al coatings obtained are non-fully homogeneous in terms of coating morphology and thickness distribution. In this work we electrodeposited Al coatings from a 3-butyl-1-ethylimidazolium tetrachloroaluminate electrolyte additivated with increasing concentrations of a new cost-effective additive: light aromatic naphtha solvent. Firstly, electrolytes were characterized by cyclic voltammetry, where changes in the electrochemistry of the process were identified. Then, surface characterization showed that Al coatings morphology turned out to be smoother, more homogeneous and more compact with increasing additive concentration. Furthermore, the process was scaled up to flat plates of 18 cm area and also on 25 cm parts designed with straight corners to demonstrate both the optimization of the electrolytic bath performance and its throwing power enhancement.

摘要

铝电沉积可以从几种离子液体电解质配方中进行。然而,由于电解质的耐久性以及所获得的铝涂层在涂层形态和厚度分布方面不完全均匀,到目前为止,这种电镀工艺尚未实现工业化。在这项工作中,我们从一种3-丁基-1-乙基咪唑四氯铝酸盐电解质中电沉积铝涂层,该电解质添加了浓度不断增加的一种新型经济高效添加剂:轻质芳烃石脑油溶剂。首先,通过循环伏安法对电解质进行表征,确定了该过程电化学的变化。然后,表面表征表明,随着添加剂浓度的增加,铝涂层的形态变得更光滑、更均匀且更致密。此外,该工艺扩大到了面积为18平方厘米的平板以及设计有直角的25厘米部件上,以展示电解槽性能的优化及其深镀能力的提高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bcf0/6682929/5a90350b0cf4/OPEN-8-1094-g001.jpg

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