氮化碳有机光催化的新兴概念

Emerging Concepts in Carbon Nitride Organic Photocatalysis.

作者信息

Mazzanti Stefano, Savateev Aleksandr

机构信息

Department of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces Research Campus Golm, Am Mühlenberg 1, 14476, Potsdam, Germany.

出版信息

Chempluschem. 2020 Nov;85(11):2499-2517. doi: 10.1002/cplu.202000606.

Abstract

Carbon nitrides encompass a class of transition-metal-free materials possessing numerous advantages such as low cost (few Euros per gram), high chemical stability, broad tunability of redox potentials and optical bandgap, recyclability, and a high absorption coefficient (>10  cm ), which make them highly attractive for application in photoredox catalysis. In this Review, we classify carbon nitrides based on their unique properties, structure, and redox potentials. We summarize recently emerging concepts in heterogeneous carbon nitride photocatalysis, with an emphasis on the synthesis of organic compounds: 1) Illumination-Driven Electron Accumulation in Semiconductors and Exploitation (IDEASE); 2) singlet-triplet intersystem crossing in carbon nitride excited states and related energy transfer; 3) architectures of flow photoreactors; and 4) dual metal/carbon nitride photocatalysis. The objective of this Review is to provide a detailed overview regarding innovative research in carbon nitride photocatalysis focusing on these topics.

摘要

碳氮化物是一类不含过渡金属的材料,具有许多优点,如低成本(每克几欧元)、高化学稳定性、氧化还原电位和光学带隙的广泛可调性、可回收性以及高吸收系数(>10 cm),这些特性使其在光氧化还原催化应用中极具吸引力。在本综述中,我们根据碳氮化物的独特性质、结构和氧化还原电位对其进行分类。我们总结了非均相碳氮化物光催化中最近出现的概念,重点是有机化合物的合成:1)半导体中的光照驱动电子积累与利用(IDEASE);2)碳氮化物激发态中的单重态-三重态系间窜越及相关能量转移;3)流动光反应器的结构;4)双金属/碳氮化物光催化。本综述的目的是提供关于碳氮化物光催化中聚焦于这些主题的创新研究的详细概述。

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