管状烯

Tubularenes.

作者信息

Mirzaei Saber, Castro Edison, Sánchez Raúl Hernández

机构信息

Department of Chemistry, University of Pittsburgh 219 Parkman Ave. Pittsburgh Pennsylvania 15260 USA

出版信息

Chem Sci. 2020 Jul 14;11(31):8089-8094. doi: 10.1039/d0sc03384g.

Abstract

We report the synthesis and characterization of conjugated, conformationally rigid, and electroactive carbon-based nanotubes that we term tubularenes. These structures are constructed from a resorcin[ ]arene base. Cyclization of the conjugated aromatic nanotube is achieved in one-pot eight-fold C-C bond formation Suzuki-Miyaura cross-coupling. DFT calculations indicate a buildup of strain energy in excess of 90 kcal mol. The resulting architectures contain large internal void spaces >260 Å, are fluorescent, and able to accept up to 4 electrons. This represents the first scaffolding approach that provides conjugated nanotube architectures.

摘要

我们报道了共轭、构象刚性且具有电活性的碳基纳米管(我们称之为管状烯)的合成与表征。这些结构由间苯二酚[ ]芳烃碱构建而成。共轭芳香纳米管的环化通过一锅法八重C-C键形成的铃木-宫浦交叉偶联反应实现。密度泛函理论计算表明应变能积累超过90千卡/摩尔。所得结构包含大于260 Å的大内部空隙空间,具有荧光性,并且能够接受多达4个电子。这代表了第一种提供共轭纳米管结构的支架构建方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd31/8163370/93975b3bb31a/d0sc03384g-s1.jpg

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