Scopoli is native to Europe and western Asia and is considered an invasive plant in China. In this study, the complete chloroplast genome of was obtained using high-throughput next-generation sequencing technology. The whole chloroplast genome was 153,017 bp long with a GC content of 38% and comprised 130 genes (86 protein-coding genes, 36 tRNA genes, and 8 rRNA genes). Phylogenetic analysis based on the concatenated chloroplast protein-coding sequences showed that is most closely related to This study provides valuable genetic data for further phylogenetic analysis and molecular identification of species in the genus .