Rochon F D, Breau L
Département de Chimie, Université du Québec à Montréal, Canada.
Acta Crystallogr C. 1999 Aug 15;55 ( Pt 8):1373-5. doi: 10.1107/s0108270199005557.
The title compound, C21H24N2O4S, containing 2-isoxazoline and oxazolidine moieties, was studied in order to determine its relative configuration, which could not be determined unambiguously by NMR techniques. The results have shown that the substituents on the three C atoms of the oxazolidine cycle are all on the same side of the ring, while the aromatic group of the toluene-4-sulfonate substituent on the N atom is located on the opposite side. The 2-isoxazoline ring was found to have the 5'S* configuration.
标题化合物C21H24N2O4S含有异恶唑啉和恶唑烷部分,为确定其相对构型而进行了研究,该构型无法通过核磁共振技术明确确定。结果表明,恶唑烷环三个碳原子上的取代基都在环的同一侧,而氮原子上对甲苯磺酸酯取代基的芳基位于相反一侧。发现2-异恶唑啉环具有5'S*构型。