Miyazawa M, Wada T, Kameoka H
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, Kowakae, Higashiosaka-shi, Osaka 577, Japan.
J Agric Food Chem. 1998 Jan 19;46(1):300-303. doi: 10.1021/jf970142l.
(+)-Limonene was mixed in an artificial diet at a concentration of 1 mg/g of diet, and the diet was fed to the last instar larvae of common cutworm (Spodopteralitura). Metabolites were recovered from frass and analyzed spectroscopically. (+)-Limonene was transformed mainly to (+)-p-menth-1-ene-8,9-diol (uroterpenol) and (+)-p-mentha-1,8-dien-7-oic acid (perillic acid). Similarly, (-)-limonene was transformed mainly to (-)-p-menth-1-ene-8,9-diol (uroterpenol) and (-)-p-mentha-1,8-dien-7-oic acid (perillic acid). The results indicate that there is little difference in metabolic pathway between the (+)- and (-)-forms.
将(+)-柠檬烯以1毫克/克饲料的浓度混入人工饲料中,并将该饲料喂给斜纹夜蛾(Spodoptera litura)的末龄幼虫。从粪便中回收代谢产物并进行光谱分析。(+)-柠檬烯主要转化为(+)-对-薄荷-1-烯-8,9-二醇(尿萜醇)和(+)-对-薄荷-1,8-二烯-7-酸(紫苏酸)。同样,(-)-柠檬烯主要转化为(-)-对-薄荷-1-烯-8,9-二醇(尿萜醇)和(-)-对-薄荷-1,8-二烯-7-酸(紫苏酸)。结果表明,(+)-型和(-)-型在代谢途径上差异不大。