Adsorption of Fluids in Pores Formed between Two Hard Cylinders.

We study adsorption in pores with curved hard walls that are made of two uniaxial cylinders by using a density functional approach. Two cases are considered: adsorption of hard spheres and adsorption of a Lennard-Jones fluid. In the case of hard spheres, we perform a comparison with the results of grand canonical ensemble Monte Carlo data. This comparison indicates that the applied approach is capable of reproducing the fluid structure quite satisfactorily. For hard spheres, we also make a comparison of the total adsorption effect (expressed as the average density of a confined fluid) inside pores with curved walls with that evaluated for a slitlike pore. We have found that the differences between adsorption in pores with curved walls and in slits with the same wall-to-wall distance are quite low. The calculations for the Lennard-Jones fluid have been concerned with the investigation of the capillary evaporation and with the evaluation of phase diagrams for different pores, including slitlike pores. We have found that the curvature of the pore walls shifts the transition toward lower values of the chemical potential and increases slightly the value of the critical temperature in comparison with the values obtained for a slitlike pore. Copyright 2000 Academic Press.