Chiang Y M, Su J K, Liu Y H, Kuo Y H
Department of Chemistry, National Taiwan University, Taipei, Republic of China.
Chem Pharm Bull (Tokyo). 2001 May;49(5):581-3. doi: 10.1248/cpb.49.581.
Four new cyclopropyl-triterpenes, 27-nor-3beta-hydroxy-25-oxocycloartane (1), (22E)-25,26,27-trinor-3beta-hydroxycycloart-22-en-24-al (2), 3beta-acetoxy-15alpha-hydroxy-13,27-cyclours-11-ene (3), 3beta-acetoxy-12alpha-formyloxy-13,27-cycloursan-11alpha-ol (4), together with (23E)-27-nor-3beta-hydroxycycloart-23-en-25-one (5) were isolated from the aerial roots of Ficus microcarpa. Compounds 3 and 4 are rare 13,27-cycloursane-type triterpenes. Their structures were elucidated by spectroscopic and chemical methods.
从榕树气生根中分离得到4个新的环丙基三萜类化合物,分别为27-降-3β-羟基-25-氧代环阿尔廷烷(1)、(22E)-25,26,27-三降-3β-羟基环阿尔廷-22-烯-24-醛(2)、3β-乙酰氧基-15α-羟基-13,27-环乌苏-11-烯(3)、3β-乙酰氧基-12α-甲酰氧基-13,27-环乌苏烷-11α-醇(4),以及(23E)-27-降-3β-羟基环阿尔廷-23-烯-25-酮(5)。化合物3和4是罕见的13,27-环乌苏烷型三萜类化合物。通过光谱和化学方法阐明了它们的结构。