Willie S N
Institute for National Measurement Standards, National Research Council of Canada, Ottawa, Ontario.
Fresenius J Anal Chem. 2001 Jun;370(2-3):131-3. doi: 10.1007/s002160100747.
The environmental CRMs currently available from NRC Ottawa comprise four natural waters for trace elements, four biological tissues for trace elements and methylmercury, three marine sediments for major and trace elements (one sediment has certified values for butyltins) and one fish tissue for organochlorines (PCBs, dioxins). Although significant effort has been expended to maintain this suite of materials, several new initiatives have also recently been completed or are in progress. The certified value for arsenobetaine in Dogfish Muscle CRM DORM-2 has been established. The certification approaches, as well as the studies to determine extraction efficiency of this organoarsenic compound, are presented. A stability study has been completed for Hg in a natural water sample and plans are underway for production of a CRM. Assessment of micronutrient stability in seawater for the purposes of CRM production is continuing and progress on this initiative is discussed.
加拿大国家研究委员会渥太华分部目前提供的环境标准物质包括四种用于痕量元素分析的天然水、四种用于痕量元素和甲基汞分析的生物组织、三种用于主量和痕量元素分析的海洋沉积物(一种沉积物有丁基锡的标准值)以及一种用于有机氯(多氯联苯、二噁英)分析的鱼类组织。尽管为维护这套物质付出了巨大努力,但最近也完成了几项新举措或正在进行中。已确定鲨鱼肌肉标准物质DORM - 2中砷甜菜碱的标准值,并介绍了认证方法以及确定该有机砷化合物提取效率的研究。已完成了一份天然水样中汞的稳定性研究,并且正在计划生产一种标准物质。为生产标准物质而对海水中微量营养素稳定性进行的评估仍在继续,并讨论了该举措的进展情况。