Becker L, Popp B, Rust T, Bada J L
Hawaii Institute of Geophysics and Planetology, University of Hawaii at Manoa, Honolulu 96822, USA.
Earth Planet Sci Lett. 1999 Mar 30;167(1-2):71-9. doi: 10.1016/s0012-821x(99)00014-x.
Stable carbon isotope measurements of the organic matter associated with the carbonate globules and the bulk matrix material in the ALH84001 Martian meteorite indicate that two distinct sources are present in the sample. The delta 13C values for the organic matter associated with the carbonate globules averaged -26% and is attributed to terrestrial contamination. In contrast, the delta 13C values for the organic matter associated with the bulk matrix material yielded a value of -15%. The only common sources of carbon on the Earth that yield similar delta 13C values, other then some diagenetically altered marine carbonates, are C4 plants. A delta 13C value of -15%, on the other hand, is consistent with a kerogen-like component, the most ubiquitous form of organic matter found in carbonaceous chondrites such as the Murchison meteorite. Examination of the carbonate globules and bulk matrix material using laser desorption mass spectrometry (LDMS) indicates the presence of a high molecular weight organic component which appears to be extraterrestrial in origin, possibly derived from the exogenous delivery, of meteoritic or cometary debris to the surface of Mars.
对ALH84001火星陨石中与碳酸盐小球及整体基质物质相关的有机物进行的稳定碳同位素测量表明,该样本中存在两种不同的来源。与碳酸盐小球相关的有机物的δ13C值平均为-26‰,这归因于地球污染。相比之下,与整体基质物质相关的有机物的δ13C值为-15‰。地球上除了一些经成岩作用改变的海洋碳酸盐外,能产生类似δ13C值的唯一常见碳源是C4植物。另一方面,-15‰的δ13C值与类干酪根成分一致,这是在默奇森陨石等碳质球粒陨石中发现的最普遍的有机物形式。使用激光解吸质谱法(LDMS)对碳酸盐小球和整体基质物质进行检测,结果表明存在一种高分子量有机成分,其似乎起源于地球之外,可能是由陨石或彗星碎片向火星表面的外源输送所致。