Raulin F, Coll P, Smith N, Benilan Y, Bruston P, Gazeau M C
LISA, CNRS, Creteil, France.
Adv Space Res. 1999;24(4):453-60. doi: 10.1016/s0273-1177(99)00087-3.
Titan, the largest satellite of Saturn, with a dense atmosphere very rich in organics, and many couplings in the various parts of its "geofluid", is a reference for studying prebiotic chemistry on a planetary scale. New data have been obtained from experiments simulating this organic chemistry (gas and aerosol phases), within the right ranges of temperature and a careful avoiding of any chemical contamination. They show a very good agreement with the observational data, demonstrating for the first time the formation of all the organic species already detected in Titan atmosphere including, at last, C4N2, together with many other species not yet detected in Titan. This strongly suggests the presence of more complex organics in Titan's atmosphere and surface, including high molecular weight polyynes and cyanopolyynes. The NASA-ESA Cassini-Huygens mission has been successfully launched in October 1997. The Cassini spacecraft will reach the Saturn system in 2004 and become an orbiter around Saturn, while the Huygens probe will penetrate into Titan's atmosphere. In situ measurements, in particular from Huygens GC-MS and ACP instruments, will provide a detailed analysis of the organics present in the air, aerosols, and surface. This very ambitious mission should yield much information of crucial importance for our knowledge of the complexity of Titan's chemistry, and, more generally for the field of exobiology.
土卫六是土星最大的卫星,拥有富含有机物的浓厚大气层,其“地球流体”各部分之间存在许多耦合现象,是在行星尺度上研究前体化学的一个参考对象。已通过在合适的温度范围内模拟这种有机化学(气相和气溶胶相)并小心避免任何化学污染的实验获得了新数据。这些数据与观测数据非常吻合,首次证明了在土卫六大气层中已检测到的所有有机物种的形成,最终包括C4N2,以及许多尚未在土卫六上检测到的其他物种。这有力地表明土卫六的大气层和表面存在更复杂的有机物,包括高分子量的多炔和氰基多炔。美国国家航空航天局(NASA)和欧洲航天局(ESA)的卡西尼-惠更斯任务于1997年10月成功发射。卡西尼号航天器将于2004年抵达土星系统并成为环绕土星的轨道器,而惠更斯探测器将穿透土卫六的大气层。现场测量,特别是来自惠更斯号气相色谱-质谱仪(GC-MS)和气溶胶收集与 pyrolysis 仪器(ACP)的测量,将对空气中、气溶胶和表面存在的有机物进行详细分析。这项极具雄心的任务应该会为我们了解土卫六化学的复杂性,以及更广泛地为外星生物学领域提供许多至关重要的信息。