Udosen E D, Essien J P, Ubom R M
Department of Chemistry and Biochemistry, University of Uyo, Nigeria.
J Environ Sci (China). 2001 Jan;13(1):92-8.
The effect of organic amendments on the oil content, heavy metals concentration and pH of petroleum contaminated sandy loam ultisol obtained from Rumuekpe oil field in Emohua Local Government Area of Rivers State, Nigeria was determined. Petroleum contaminated soils were treated with wood ash, compost and sawdust. The addition of organic amendments resulted in a significant (at 95% probability level) decrease in oil content by 92% for composting, 81% for soil treated with sawdust and 58% for soil with ash supplementation, over 6 months. The effect of treatments on the iron(Fe), copper(Cu) and lead(Pb) concentration was significant at P < 0.001. The remediation also affected the pH of soil. This initial pH of 5.6 was depressed by the application of compost and sawdust supplements respectively to a final pH of 5.2 and 5.3. On the other hand, amending the soil with wood ash raised the pH from 5.6 to 6.2. Increased acidity caused a decrease in the heavy metals concentration in the contaminated soil. Soil treatment with compost generally gave the best remediation results, followed by sawdust and then ash. Adjusting the pH of oil contaminated soil to high acidic levels may promote the availability and migration of heavy metals in remediated soils and not necessarily the rate of oil mineralization.
研究了有机改良剂对尼日利亚河流州埃莫华地方政府区鲁梅克佩油田受石油污染的砂质壤土富铁土的含油量、重金属浓度和pH值的影响。用木灰、堆肥和锯末处理受石油污染的土壤。添加有机改良剂后,经过6个月,堆肥处理使含油量显著(在95%概率水平)下降92%,锯末处理的土壤下降81%,添加灰分的土壤下降58%。处理对铁(Fe)、铜(Cu)和铅(Pb)浓度的影响在P<0.001时显著。修复也影响了土壤的pH值。堆肥和锯末添加分别使初始pH值5.6降至最终pH值5.2和5.3。另一方面,用木灰改良土壤使pH值从5.6提高到6.2。酸度增加导致污染土壤中重金属浓度降低。用堆肥处理土壤通常能取得最佳修复效果,其次是锯末,然后是灰分。将石油污染土壤的pH值调节到高酸性水平可能会促进修复土壤中重金属的有效性和迁移,而不一定能促进石油矿化速率。