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双功能层状有机导体κ-(BETS)₂FeBr₄中磁场诱导超导性的迹象

An indication of magnetic-field-induced superconductivity in a bifunctional layered organic conductor, kappa-(BETS)(2)FeBr(4).

作者信息

Fujiwara Hideki, Kobayashi Hayao, Fujiwara Emiko, Kobayashi Akiko

机构信息

Institute for Molecular Science, Myodaiji, Okazaki, Aichi 444-8585, Japan.

出版信息

J Am Chem Soc. 2002 Jun 19;124(24):6816-7. doi: 10.1021/ja026067z.

Abstract

Hybrid systems consisting of the conducting layers of organic donor molecules and the magnetic layers of inorganic anions have been focused on as possible bifunctional materials, whose conducting properties can be tuned by controlling the magnetic state of the anion layers on an application of magnetic field. Here we report the magnetoresistance of the antiferromagnetic organic superconductor, kappa-(BETS)2FeBr4 [BETS = bis(ethylenedithio)tetraselenafulvalene], consisting of the two-dimensional superconducting layers of the BETS semications and the insulating layers of the FeBr4- anions. Due to the metamagnetic nature of the Fe3+ spin system, characteristic resistivity decrease was observed just below the antiferromagnetic superconductor-to-ferromagnetic metal transition at 1.6 T. Furthermore, an indication of the onsets of the magnetic-field-induced superconductivity was discovered around 12.5 T.

摘要

由有机供体分子的导电层和无机阴离子的磁性层组成的混合系统,作为可能的双功能材料受到关注,其导电性能可通过在施加磁场时控制阴离子层的磁态来调节。在此,我们报道了反铁磁有机超导体κ-(BETS)2FeBr4 [BETS = 双(乙二硫基)四硒富瓦烯] 的磁电阻,它由BETS半阳离子的二维超导层和FeBr4-阴离子的绝缘层组成。由于Fe3+自旋系统的变磁性,在1.6 T时,恰好在反铁磁超导体到铁磁金属转变温度以下观察到特征电阻率下降。此外,在12.5 T左右发现了磁场诱导超导性开始的迹象。

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