聚（联萘基水杨醛锰配合物）的合成、结构及其在不对称环氧化反应中的应用

Synthesis and structure of poly(binaphthyl salen manganese complex) and its application to asymmetric epoxidation.

作者信息

Maeda Takeshi, Furusho Yoshio, Takata Toshikazu

机构信息

Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka, Japan.

出版信息

Chirality. 2002 Jul;14(7):587-90. doi: 10.1002/chir.10093.

DOI:10.1002/chir.10093

PMID:12112333

Abstract

Poly(binaphthyl salen manganese complex)es 3-Mn were synthesized from a 3,3'-diformylbinaphthol derivative, alpha,omega-diamines, and Mn(OAc)2. Their helical structures were well-supported by their IR, UV, and CD spectra. The catalysis of 3-Mn in an asymmetric epoxidation was investigated.

摘要

聚（联萘酚水杨醛锰配合物）3-Mn由3,3'-二甲酰基联萘酚衍生物、α,ω-二胺和醋酸锰（II）合成。它们的螺旋结构通过红外光谱、紫外光谱和圆二色光谱得到了有力支持。研究了3-Mn在不对称环氧化反应中的催化作用。