Dy(4)B(6)O(15)的多砧高压合成：首个具有共享边BO(4)四面体的硼酸盐。
Multianvil high-pressure synthesis of Dy(4)B(6)O(15): the first oxoborate with edge-sharing BO(4) tetrahedra.
作者信息
Huppertz Hubert, von der Eltz Benjamin
机构信息
Department of Chemistry, Ludwig-Maximilians-University of Munich, Butenandtstrasse 5-13, Germany.
出版信息
J Am Chem Soc. 2002 Aug 14;124(32):9376-7. doi: 10.1021/ja017691z.
PMID:12167024
Abstract
In all known oxoborates the linkage of BO(3) and BO(4) groups is performed via common corners. Here we present the high-pressure/high-temperature synthesis of Dy(4)B(6)O(15), which is the first oxoborate exhibiting edge-sharing BO(4) tetrahedra.
摘要
在所有已知的硼酸盐中，BO(3) 和 BO(4) 基团是通过共用角相连的。在此，我们展示了 Dy(4)B(6)O(15) 的高压/高温合成，它是首个呈现出 BO(4) 四面体边共享的硼酸盐。
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