Karaghiosoff Konstantin, Klapötke Thomas M, Michailovski Alexej, Holl Gerhard
Department of Chemistry, Ludwig-Maximilias-Universität, Butenandtstrasse 5-13 (Haus D), D-81377 München, Germany.
Acta Crystallogr C. 2002 Sep;58(Pt 9):o580-1. doi: 10.1107/S0108270102014774. Epub 2002 Aug 31.
The title compound (systematic name: 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.0(3,11).0(5,9)]dodecane), C(6)H(6)N(4)O(8), exhibits the highest density among known N-nitramines, due to its close-packed crystal structure. It may be regarded as consisting of a distorted hexagonal close-packed lattice formed by the isowurtzitane cages, with the nitro groups occupying the free space between the cages.
标题化合物(系统名称:4,10 - 二硝基 - 2,6,8,12 - 四氧杂 - 4,10 - 二氮杂四环[5.5.0.0(3,11).0(5,9)]十二烷),C(6)H(6)N(4)O(8),由于其紧密堆积的晶体结构,在已知的N - 硝胺中具有最高的密度。它可以被认为是由异伍兹烷笼形成的扭曲六方紧密堆积晶格组成,硝基占据笼之间的自由空间。