Brunker T J, Barlow S, O'Hare D
Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK OX1 3QR.
Chem Commun (Camb). 2001 Oct 21(20):2052-3. doi: 10.1039/b105661c.
(eta 5-Cyclopentadienyl)(kappa 3-hydrotris(pyrazolyl)borate)-cobalt(II) has been synthesised; magnetic and crystallographic data indicate this to be the first example of a high-spin cobalt organometallic complex whilst its pentamethylcyclopentadienyl analogue is found to have a low-spin electronic configuration.
（η⁵-环戊二烯基）（κ³-氢三（吡唑基）硼酸根）-钴（II）已被合成；磁性和晶体学数据表明这是高自旋钴有机金属配合物的首个实例，而其五甲基环戊二烯基类似物则具有低自旋电子构型。
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